Deactivation of Cd(5(3)P(J)) by H-2 and D-2: Branching ratios for the production of CdH and CdD

被引：2
|
作者：
Umemoto, H
Ohsako, N
机构：
[1] Dept. of Chemical Materials Science, Japan Adv. Inst. Sci. and Technol., Nomi, Ishikawa 923-12, Asahidai, Tatsunokuchi
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1996年 / 69卷 / 08期
关键词：
D O I：
10.1246/bcsj.69.2185
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The deactivation processes of Cd(5(3)P(1)) and Cd(5(3)P(0)) by H-2 and D-2 were examined by employing a laser excitation-depletion technique. The concentration of the ground-state Cd(5(1)S(0)) atoms was measured in both the presence and absence of an intense saturable pump laser beam. In the presence of a pump laser, the concentration decreased in accordance with the production of CdH(CdD). From this decrease, the branching ratios for the production of CdH(CdD) could be determined. The depletion was unaffected when N-2 was added. This suggests that the branching ratios are the same for Cd(5(3)P(1)) and Cd(5(3)P(0)), although the production of CdH(CdD) is endothermic for Cd(5(3)P(0)). The branching ratios were 0.81+/-0.04 for H-2 and 0.76+/-0.06 for D-2. The efficient production of CdH(CdD) from not only Cd(5(3)P(1)), but also Cd(5(3)P(0)), can be accounted for by correlational considerations.
引用
收藏
页码：2185 / 2189
页数：5
相关论文
共 50 条
  • [41] Experimental antiproton nuclear stopping power in H-2 and D-2
    Bertin, A
    Bruschi, M
    Capponi, M
    DAntone, I
    DeCastro, S
    Ferretti, A
    Galli, D
    Giacobbe, B
    Marconi, U
    Piccinini, M
    Cesari, NS
    Spighi, R
    Vecchi, S
    Vezzani, A
    Vigotti, F
    Villa, M
    Vitale, A
    Zoccoli, A
    Corradini, M
    Donzella, A
    Rizzini, EL
    Venturelli, L
    Zenoni, A
    Cicalo, C
    Masoni, A
    Puddu, G
    Serci, S
    Temnikov, P
    Usai, GL
    Ableev, VG
    Denisov, OY
    Gorchakov, OE
    Prakhov, SN
    Rozhdestvensky, AM
    Sapozhnikov, MG
    Tretyak, W
    Poli, M
    Gianotti, P
    Guaraldo, C
    Lanaro, A
    Lucherini, V
    Nichitiu, F
    Petrascu, C
    Rosca, A
    Cavion, C
    Gastaldi, U
    Lombardi, M
    Vannucci, I
    Vedovato, G
    Morando, M
    PHYSICAL REVIEW A, 1996, 54 (06): : 5441 - 5444
  • [42] INCOMMENSURATE PHASES OF H-2, HD, AND D-2 MONOLAYERS ON GRAPHITE
    CUI, J
    FAIN, SC
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1987, 5 (04): : 710 - 711
  • [43] MEASUREMENT OF H-2, D-2 SOLUBILITIES IN ZR-AL
    KNIZE, RJ
    CECCHI, JL
    DYLLA, HF
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1982, 20 (04): : 1135 - 1137
  • [44] ELECTROPRODUCTION OF RHO-O FROM H-2 AND D-2
    PUN, TP
    BAGGS, R
    FELDMAN, GJ
    HANSON, G
    LYON, DE
    MARTIN, F
    MARTIN, JF
    PERL, ML
    BOLON, C
    LANZA, RC
    LUCKEY, D
    OSBORNE, LS
    ROTH, DG
    DAKIN, JT
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1976, 21 (04): : 527 - 527
  • [45] ELECTRIC FIELD INDUCED ABSORPTION SPECTRA OF H-2 AND D-2
    TERHUNE, RW
    PETERS, CW
    SPECTROCHIMICA ACTA, 1957, 10 (02): : 219 - 219
  • [46] ELECTRIC FIELD INDUCED INFRARED ABSORPTION OF H-2 AND D-2
    CHURCH, CH
    PETERS, CW
    JOURNAL OF THE OPTICAL SOCIETY OF AMERICA, 1958, 48 (11) : 865 - 865
  • [47] MULTIPHOTON FRAGMENTATION OF H-2(+) AND D-2(+) WITH COHERENT AND INCOHERENT FIELDS
    MIRETARTES, S
    MICHA, DA
    PHYSICAL REVIEW A, 1995, 52 (04): : 2984 - 2993
  • [48] THE ADSORPTION OF H-2 AND D-2 ON FE(110) - KINETICS AND ENERGETICS
    KURZ, EA
    HUDSON, JB
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1988, 6 (03): : 774 - 775
  • [49] Studies of the positive muon behavior in solid H-2 and D-2
    Higemoto, W
    Satoh, K
    Nishida, N
    Nishiyama, K
    Nagamine, K
    HYPERFINE INTERACTIONS, 1997, 106 (1-4): : 39 - 44
  • [50] ZERO KINETIC-ENERGY PROTON AND DEUTERON PRODUCTION FROM PHOTOIONIZATION OF H-2 AND D-2
    HE, ZX
    CUTLER, JN
    SOUTHWORTH, SH
    HUGHEY, LR
    SAMSON, JAR
    JOURNAL OF CHEMICAL PHYSICS, 1995, 103 (10): : 3912 - 3916
12345