Practical and efficient synthesis of C2 symmetrical diamines with Zn/Me3SiCl

被引：0

作者：

Alexakis, A ^{[1
]}

Aujard, I ^{[1
]}

Mangeney, P ^{[1
]}

机构：

[1] Univ Paris 06, Dept Organ Chem, F-75005 Paris, France

来源：

SYNLETT | 1998年 / 08期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

C-2 symmetrical diamines are efficiently obtained by reductive coupling of imines with the couple Zn/Me3SiCl. This high yielding method is very practical and cheap for large scale preparation.

引用

页码：873 / +

页数：3

共 50 条

[11] ACYLPHOSPHONATES .6. REACTION-MECHANISM OF ZN/ME3SICL MEDIATED CONVERSION OF 2,2,2-TRICHLOROETHOXYCARBONYLPHOSPHONATES TO SILYL PHOSPHITES
FUJII, M
OZAKI, K
KUME, A
SEKINE, M
HATA, T
TETRAHEDRON LETTERS, 1986, 27 (29) : 3365 - 3368
[12] C-SILYLATION OF METHYLBUTENONE, CARBONE AND ALPHA IONONE USING SYSTEM ME3SICL/LI/THF
CALAS, R
DUNOGUES, J
EKOUYA, A
MERAULT, G
DUFFAUT, N
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 65 (01) : C4 - C6
[13] Zn-mediated catalytic photoreduction of aldimines.: One-pot synthesis and separation of meso and d,l C2 symmetrical diamines
Ortega, M
Rodríguez, MA
Campos, PJ
TETRAHEDRON, 2004, 60 (31) : 6475 - 6478
[14] REGIOSELECTIVE OPENING OF TETRAHYDROFURANNIC ALCOHOLS BY ME3SICL/NAI - SYNTHESIS OF EXO-BREVICOMINS AND ENDO-BREVICOMINS
JATCZAK, M
AMOUROUX, R
CHASTRETTE, M
TETRAHEDRON LETTERS, 1985, 26 (19) : 2315 - 2316
[15] Me3SiCl and Et3Sil-promoted one-pot synthesis of 1,4-dihydropyridine derivatives
Mirza-Aghayan, Maryam
Langrodi, Mahboubeh Khoshkameh
Rahimifard, Mahshid
Boukherroub, Rabah
APPLIED ORGANOMETALLIC CHEMISTRY, 2009, 23 (07) : 267 - 271
[16] ME3SICL/HMPA ACCELERATED CONJUGATE ADDITION OF CATALYTIC COPPER REAGENT - STEREOSELECTIVE SYNTHESIS OF ENOL SILYL ETHER OF ALDEHYDE
HORIGUCHI, Y
MATSUZAWA, S
NAKAMURA, E
KUWAJIMA, I
TETRAHEDRON LETTERS, 1986, 27 (34) : 4025 - 4028
[17] ME3SICL-NAI-CH3CN AS AN EFFICIENT AND PRACTICAL REDUCING AGENT FOR BENZYLIC ALCOHOLS
SAKAI, T
MIYATA, K
UTAKA, M
TAKEDA, A
TETRAHEDRON LETTERS, 1987, 28 (33) : 3817 - 3818
[18] Synthesis of novel C2 symmetrical and enantiomerically pure thiepines
Hudson, A
Orpen, AG
Phetmung, H
Wyatt, P
TETRAHEDRON LETTERS, 1999, 40 (04) : 813 - 816
[19] Difluoromethylthiolation of Phenols and Related Compounds with a HF2CSO2Na/Ph2PCl/Me3SiCl System
Huang, Zhongyan
Matsubara, Okiya
Jia, Shichong
Tokunaga, Etsuko
Shibata, Norio
ORGANIC LETTERS, 2017, 19 (04) : 934 - 937
[20] A practical and efficient synthesis of chiral N,N-disubstituted C2 symmetric diamines derived from (R,R)-1,2-diaminocyclohexane
Alexakis, A
Chauvin, AS
Stouvenel, R
Vrancken, E
Mutti, S
Mangeney, P
TETRAHEDRON-ASYMMETRY, 2001, 12 (08) : 1171 - 1178

← 1 2 3 4 5 →