Synthesis of novel high-performance polymers via Pd-catalyzed amination of dibromoarenes with primary aromatic diamines

被引：34
|
作者：
Chang, Guanjun
Luo, Xuan
Zhang, Lin
Lin, Runxiong [1 ]
机构：
[1] Qingdao Univ Sci & Technol, Key Lab Rubber Plast, Minist Educ, Qingdao 266042, Peoples R China
[2] China Acad Engn Phys, Mianyang 621900, Peoples R China
来源：
MACROMOLECULES | 2007年 / 40卷 / 24期
关键词：
D O I：
10.1021/ma070679s
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A series of novel polymers have been obtained by the condensation polymerization of different dibromoarenes with different primary aromatic diamines via palladium-catalyzed aryl amination reaction. The structures of polymers are characterized by means of FT-IR, H-1 NMR spectroscopy, and elemental analysis; the results show an agreement with the proposed structure. DSC and TG measurements show that polymers possess high glass transition temperature (T-g > 170 degrees C) and good thermal stability with high decomposition temperatures (T-D > 450 degrees C). Thesis novel polymers also exhibit good mechanical behavior and good solubility.
引用
收藏
页码：8625 / 8630
页数：6
相关论文
共 50 条
  • [31] One-Pot Synthesis of Highly Substituted Aromatic Amine Derivatives via Pd-Catalyzed Aminobenzannulation Reaction
    Gou, Fa-Rong
    Huo, Peng-Fei
    Bi, Hai-Peng
    Guan, Zheng-Hui
    Liang, Yong-Min
    ORGANIC LETTERS, 2009, 11 (15) : 3418 - 3421
  • [32] Synthesis of Secondary Aromatic Amides via Pd-Catalyzed Aminocarbonylation of Aryl Halides Using Carbamoylsilane as an Amide Source
    Tong, Wenting
    Cao, Pei
    Liu, Yanhong
    Chen, Jianxin
    JOURNAL OF ORGANIC CHEMISTRY, 2017, 82 (21): : 11603 - 11608
  • [33] Synthesis of Chiral 2-trifluoromethyl-4-(tetrahydroquinolinyl)-4H-chromenes via Pd-Catalyzed Asymmetric Amination
    Wang, Bangzhong
    Sun, Luyang
    Zhang, Pengyue
    Zhang, Shuaibo
    Zhao, Jinfeng
    Qu, Jingping
    Zhou, Yuhan
    ADVANCED SYNTHESIS & CATALYSIS, 2025,
  • [34] SYNTHESIS OF POLYAZAMACROCYCLES COMPRISING 6,6′-DIAMINO-2,2′-BIPYRIDINE MOIETIES VIA Pd-CATALYZED AMINATION
    Averin, Alexei D.
    Uglov, Alexei N.
    Buryak, Alexei K.
    Bessmertnykh, Alla G.
    Guilard, Roger
    Beetskaya, Irina P.
    HETEROCYCLES, 2010, 80 (02) : 957 - 975
  • [35] Synthesis of Conjugated Polymers Containing Octafluorobiphenylene Unit via Pd-Catalyzed Cross-Dehydrogenative-Coupling Reaction
    Aoki, Hideaki
    Saito, Hitoshi
    Shimoyama, Yuto
    Kuwabara, Junpei
    Yasuda, Takeshi
    Kanbara, Takaki
    ACS MACRO LETTERS, 2018, 7 (01) : 90 - 94
  • [36] Enantioselective synthesis of 1-vinyltetrahydroisoquinolines through Pd-catalyzed intramolecular asymmetric allylic amination using novel monophosphoramidite ligands
    Chien, Chih-Wei
    Ojima, Iwao
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [37] Synthesis and Electrochemical Properties of Novel Redox-Active Polymers with Anthraquinone Moieties by Pd-catalyzed Cyclopolymerization of Dienes
    Motokuni, Kenya
    Haeupler, Bernard
    Burges, Rene
    Hager, Martin D.
    Schubert, Ulrich S.
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2016, 54 (14) : 2184 - 2190
  • [38] Novel synthesis of bridged phenylthienylethenes and dithienylethenes via Pd-catalyzed double-cyclization reactions of diarylhexadienynes
    Rahman, SMA
    Sonoda, M
    Ono, M
    Miki, K
    Tobe, Y
    ORGANIC LETTERS, 2006, 8 (06) : 1197 - 1200
  • [39] Synthesis of Novel Aryl and Heteroaryl Acyl Sulfonimidamides via Pd-Catalyzed Carbonylation Using a Nongaseous Precursor
    Borhade, Sanjay R.
    Sandstrom, Anja
    Arvidsson, Per I.
    ORGANIC LETTERS, 2013, 15 (05) : 1056 - 1059
  • [40] Synthesis of phthalic acid derivatives via Pd-catalyzed alkoxycarbonylation of aromatic C-H bonds with alkyl chloroformates
    Liao, Gang
    Chen, Hao-Ming
    Shi, Bing-Feng
    CHEMICAL COMMUNICATIONS, 2018, 54 (77) : 10859 - 10862
12345