Consider a differential equation y' = A(t,y)y, y(0) = y(0) with y(0) is an element of G and A : R+ x G --> g, where a is a Lie algebra of the matricial Lie group G. Every B is an element of g can be mapped to G by the matrix exponential map exp (tB) with t is an element of B. Most numerical methods for solving ordinary differential equations (ODEs) on Lie groups are based on the idea of representing the approximation y(n) of the exact solution y(t(n)) t, is an element of R+, by means of exact exponentials of suitable elements of the Lie algebra, applied to the initial value y(0) This ensures that y(n) is an element of G. When the exponential is difficult to compute exactly, as is the case when the dimension is large, an approximation of exp (tB) plays an important role in the numerical solution of ODEs on Lie groups. In some cases rational or polynomial approximants are unsuitable and we consider alternative techniques, whereby exp(tB) is approximated by a product of simpler exponentials. In this paper we present some ideas based on the use of the Strang splitting for the approximation of matrix exponentials. Several cases of B and G are considered, in tandem with general theory. Order conditions are discussed, and a number of numerical experiments conclude the paper.