The syntheses, crystal, molecular and electronic structures of two polymorphs of [ReCl2(N2COPh)(C3N2H4)(PPh3)2] and [ReCl2(N2COPh)(py)(PPh3)2] complexes

被引：6

作者：

Dziegielewski, JO

Michalik, S

Kruszynski, R

Bartczak, TJ

Kusz, J

机构：

[1] Silesian Univ, Inst Chem, Dept Inorgan & Radiat Chem, PL-40006 Katowice, Poland

[2] Tech Univ Lodz, Inst Gen & Ecol Chem, Xray Crystallog Lab, PL-90924 Lodz, Poland

[3] Silesian Univ, Inst Phys, PL-40006 Katowice, Poland

来源：

POLYHEDRON | 2003年 / 22卷 / 25-26期

关键词：

rhenium; organodiazenido; X-ray structures; electronic structures;

D O I：

10.1016/j.poly.2003.07.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [ReCl2(eta(2)-NZCOPh-N',O)(PPh3)(2)] complex reacts with pyridine and pyrazole to give [ReCl2(N2COPh)(py)(PPh3)(2)] and [ReCl2(N2COPh)(C3N2H4)(PPh3)(2)], respectively. Two monoclinic polymers of [ReCl2(NZCOPh)(C3N2H4)(PPh3)(2)] and [ReCl2(N2COPh)(py)(PPh3)(2)] have been characterized by IR, UV-Vis, H-1 NMR, magnetic measurements and X-ray structure. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：3307 / 3313

页数：7

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