Synthesis and fluorescence spectroscopy of tris(pyrenyl)pnictogen compounds

被引：13
|
作者：
Behm, Kira [1 ]
Essner, Jeremy B. [1 ]
Barnes, Charles L. [1 ]
Baker, Gary A. [1 ]
Walensky, Justin R. [1 ]
机构：
[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
来源：
DALTON TRANSACTIONS | 2017年 / 46卷 / 33期
关键词：
PYRENE; TRIPHENYLPHOSPHINE; STATE;
D O I：
10.1039/c7dt01953j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis, characterization, and fluorescence spectroscopy of E(C16H9)(3) complexes (E = P, As, Sb, and Bi), as well as OP(C16H9)(3), OAs(C16H9)(3), and SP(C16H9)(3), is reported. These compounds exhibit fluorescence quantum yields that span two orders of magnitude, from well below 1% to ca. 14%.
引用
收藏
页码：10867 / 10875
页数：9
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