Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state

被引：79

作者：

Silver, Mark A. ^{[1
]}

Cary, Samantha K. ^{[1
]}

Johnson, Jason A. ^{[2
]}

Baumbach, Ryan E. ^{[3
]}

Arico, Alexandra A. ^{[1
]}

Luckey, Morgan ^{[4
,5
]}

Urban, Matthew ^{[4
,5
]}

Wang, Jamie C. ^{[1
]}

Polinski, Matthew J. ^{[6
]}

Chemey, Alexander ^{[1
]}

Liu, Guokui ^{[7
]}

Chen, Kuan-Wen ^{[3
]}

Van Cleve, Shelley M. ^{[8
]}

Marsh, Matthew L. ^{[1
]}

Eaton, Teresa M. ^{[1
]}

de Burgt, Lambertus J. van ^{[1
]}

Gray, Ashley L. ^{[2
]}

Hobart, David E. ^{[1
]}

Hanson, Kenneth ^{[1
]}

Maron, Laurent ^{[9
]}

Gendron, Frederic ^{[10
]}

Autschbach, Jochen ^{[10
]}

Speldrich, Manfred ^{[11
]}

Koegerler, Paul ^{[11
]}

Yang, Ping ^{[12
]}

Braley, Jenifer ^{[4
,5
]}

Albrecht-Schmitt, Thomas E. ^{[1
]}

机构：

[1] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA

[2] Florida State Univ, Environm Hlth & Safety, Tallahassee, FL 32306 USA

[3] Natl High Magnet Field Lab, Tallahassee, FL 32310 USA

[4] Colorado Sch Mines, Dept Chem & Geochem, Golden, CO 80401 USA

[5] Colorado Sch Mines, Dept Nucl Engn, Golden, CO 80401 USA

[6] Bloomsburg Univ Penn, Dept Chem & Biochem, Bloomsburg, PA 17815 USA

[7] Argonne Natl Lab, Chem Sci & Engn Div, 9700 S Cass Ave, Argonne, IL 60439 USA

[8] Oak Ridge Natl Lab, Nucl Mat Proc Grp, One Bethel Valley Rd, Oak Ridge, TN 37830 USA

[9] Inst Natl Sci Appl, Lab Phys & Chim Nanoobjets, F-31077 Toulouse 4, France

[10] SUNY Buffalo, Univ Buffalo, Dept Chem, Buffalo, NY 14260 USA

[11] Univ Aachen, Inst Anorgan Chem, Rheinisch Westfal Tech Hsch, D-52074 Aachen, Germany

[12] Los Alamos Natl Lab, Div Theory, Los Alamos, NM 87545 USA

来源：

SCIENCE | 2016年 / 353卷 / 6302期

基金：

欧洲研究理事会; 美国国家科学基金会;

关键词：

MOLECULAR-ORBITAL METHODS; VALENCE BASIS-SETS; TRIVALENT ACTINIDE; CRYSTAL-STRUCTURES; CALIFORNIUM; ENERGY; ELEMENT; COVALENCY; PLUTONIUM(III); SPECTRA;

D O I：

10.1126/science.aaf3762

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Berkelium is positioned at a crucial location in the actinide series between the inherently stable half-filled 5f(7) configuration of curium and the abrupt transition in chemical behavior created by the onset of a metastable divalent state that starts at californium. However, the mere 320-day half-life of berkelium's only available isotope, Bk-249, has hindered in-depth studies of the element's coordination chemistry. Herein, we report the synthesis and detailed solid-state and solution-phase characterization of a berkelium coordination complex, Bk(III)tris(dipicolinate), as well as a chemically distinct Bk(III) borate material for comparison. We demonstrate that berkelium's complexation is analogous to that of californium. However, from a range of spectroscopic techniques and quantum mechanical calculations, it is clear that spin-orbit coupling contributes significantly to berkelium's multiconfigurational ground state.

引用

页数：8

共 50 条

[21] Solid-State and Solution Characterization of Myricetin
Franklin, Stephen J.
Myrdal, Paul B.
AAPS PHARMSCITECH, 2015, 16 (06): : 1400 - 1408
[22] Leaching of borate waste cement matrices:: pore solution and solid phase characterization
Hernández, S
Guerrero, A
Goñi, S
ADVANCES IN CEMENT RESEARCH, 2000, 12 (01) : 1 - 8
[23] Transient Radiation-Induced Berkelium(III) and Californium(III) Redox Chemistry in Aqueous Solution
Horne, Gregory P.
Rotermund, Brian M.
Grimes, Travis S.
Sperling, Joseph M.
Meeker, David S.
Zalupski, Peter R.
Beck, Nicholas
Huffman, Zachary K.
Martinez, Daniela Gomez
Beshay, Andrew
Peterman, Dean R.
Layne, Bobby H.
Johnson, Jason
Cook, Andrew R.
Albrecht-Schonzart, Thomas E.
Mezyk, Stephen P.
INORGANIC CHEMISTRY, 2022, 61 (28) : 10822 - 10832
[24] BERKELIUM CHEMISTRY IN COMPLEXING AQUEOUS-SOLUTIONS AND IN THE SOLID-STATE
HOBART, DE
MORRIS, DE
PALMER, PD
HAIRE, RG
PETERSON, JR
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 78 - NUCL
[25] The Composition and Structure of Iron(III) Complex Compounds With Salicylic Acid in Ethanol Solution and in The Solid Thin Film State
Khalipova, Olga
Kuznetsova, Svetlana
Kozik, Vladimir
PROSPECTS OF FUNDAMENTAL SCIENCES DEVELOPMENT (PFSD-2016), 2016, 1772
[26] Absorption and lumiescence spectra of Eu(III) complexes with oxydiacetate and dipicolinate in aqueous solution
Kim, JG
Yoon, SK
Kang, JG
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1996, 17 (09) : 854 - 857
[27] PROTONATION OF TETRAKIS(PYRAZOL-1-YL)-BORATE IN THE SOLID-STATE AND IN SOLUTION
LOPEZ, C
CLARAMUNT, RM
FOCESFOCES, C
CANO, FH
ELGUERO, J
REVUE ROUMAINE DE CHIMIE, 1994, 39 (07) : 795 - 805
[28] Solid state and solution structures of rhodium and iridium poly(pyrazolyl)borate diene complexes
Adams, Christopher J.
Anderson, Kirsty M.
Charmant, Jonathan P. H.
Connelly, Neil G.
Field, Bevis A.
Hallett, Andrew J.
Horne, Mathew
DALTON TRANSACTIONS, 2008, (20) : 2680 - 2692
[29] Characterization of Pharmaceutical Compounds by Solid-state NMR
Vogt, Frederick G.
EMAGRES, 2015, 4 (02): : 255 - 268
[30] Characterization of nitrogenated compounds in solid state fermented bran
da Silveirai, Cristina Moreira
Furlong, Eliana Badiale
CIENCIA E TECNOLOGIA DE ALIMENTOS, 2007, 27 (04): : 805 - 811

← 1 2 3 4 5 →