Preparation and characterization of chiral copper 12-metallacrown-4 complexes, inorganic analogues of tetraphenylporphyrinatocopper(II)

被引：45
|
作者：
Halfen, JA [1 ]
Bodwin, JJ [1 ]
Pecoraro, VL [1 ]
机构：
[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
来源：
INORGANIC CHEMISTRY | 1998年 / 37卷 / 21期
关键词：
D O I：
10.1021/ic9807386
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Chiral 12-metallacrown-4 complexes can now be obtained in high yield using resolved beta-phenylalanine hydroxamic acids as organic scaffolding. These new copper(II) compounds bear a striking resemblance based on size and shape to Cu(II) tetraphenylporphyrin. This suggests that metallacrowns may be useful alternatives to metalloporphyrins in future applications which require high metal densities and well-defined chiral centers.
引用
收藏
页码：5416 / +
页数：3
相关论文
共 50 条
  • [11] Lanthanide(III)-induced conversion of 12-metallacrown-4 to 5-metallacrown-5 complexes in solution
    Pacco, A
    Parac-Vogt, TN
    van Besien, E
    Pierloot, K
    Görller-Walrand, C
    Binnemans, K
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (16) : 3303 - 3310
  • [12] Slow Magnetic Relaxation of a 12-Metallacrown-4 Complex with a Manganese(III)-Copper(II) Heterometallic Ring Motif
    Lewis, Alex J.
    Garlatti, Elena
    Cugini, Francesco
    Solzi, Massimo
    Zeller, Matthias
    Carretta, Stefano
    Zaleski, Curtis M.
    INORGANIC CHEMISTRY, 2020, 59 (17) : 11894 - 11900
  • [13] COPPER(II) 12-METALLACROWN-4 - SYNTHESIS, STRUCTURE, LIGAND VARIABILITY, AND SOLUTION DYNAMICS IN THE 12-MC-4 STRUCTURAL MOTIF
    GIBNEY, BR
    KESSISSOGLOU, DP
    KAMPF, JW
    PECORARO, VL
    INORGANIC CHEMISTRY, 1994, 33 (22) : 4840 - 4849
  • [14] Synthesis, Structural, and Magnetic Characterization of a Mixed 3d/4f 12-Metallacrown-4 Family of Complexes
    Athanasopoulou, Angeliki A.
    Carrella, Luca M.
    Rentschler, Eva
    INORGANICS, 2018, 6 (03):
  • [15] A three-dimensional copper(II) 12-metallacrown-4 complex with malonomonohydroxamic acid (H3mmh) as a ligand
    Lago, Ana B.
    Pasan, Jorge
    Canadillas-Delgado, Laura
    Fabelo, Oscar
    Casado, Francisco J. M.
    Julve, Miguel
    Lloret, Francesc
    Ruiz-Perez, Catalina
    NEW JOURNAL OF CHEMISTRY, 2011, 35 (09) : 1817 - 1822
  • [16] Crystal structure and magnetic properties of a pentanuclear copper(II) 12-metallacrown-4 complex derived from glutaroimide-dioxime
    Liu, Xiao-Meng
    Li, Xue-Qi
    Wang, Qing-Lun
    Liu, Qian-Ying
    Tong, Yu-Zhang
    Jia, Xiao-Pu
    Yang, Chun
    INORGANIC CHEMISTRY COMMUNICATIONS, 2020, 118
  • [17] A systematic study of ligand chirality in 12-metallacrown-4 structures: A route to new chiral materials.
    Bodwin, JJ
    Pecoraro, VL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U1013 - U1013
  • [18] Magnetic and Sorption Properties of Supramolecular Systems Based on Pentanuclear Copper(II) 12-Metallacrown-4 Complexes and Isomeric Phthalates: Structural Modeling of the Different Stages of Alcohol Sorption
    Pavlishchuk, Anna V.
    Kolotilov, Sergey V.
    Zeller, Matthias
    Shvets, Oleksiy V.
    Fritsky, Igor O.
    Lofland, Samuel E.
    Addison, Anthony W.
    Hunter, Allen D.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (31) : 4826 - 4836
  • [19] Unexpected formation of a copper(II) 12-metallacrown-4 with (S)-glutamic-γ-hydroxamic acid:: a thermodynamic and spectroscopic study in aqueous solution
    Tegoni, M
    Dallavalle, F
    Belosi, B
    Remelli, M
    DALTON TRANSACTIONS, 2004, (09) : 1329 - 1333
  • [20] Four Mixed 3d-4f 12-Metallacrown-4 Complexes: Syntheses, Structures and Magnetic Properties
    Qin, Yaru
    Gao, Qian
    Chen, Yanmei
    Liu, Wei
    Lin, Feng
    Zhang, XiangFei
    Dong, Yaping
    Li, Yahong
    JOURNAL OF CLUSTER SCIENCE, 2017, 28 (03) : 891 - 903
12345