Preparation and characterization of chiral copper 12-metallacrown-4 complexes, inorganic analogues of tetraphenylporphyrinatocopper(II)

被引：45
|
作者：
Halfen, JA [1 ]
Bodwin, JJ [1 ]
Pecoraro, VL [1 ]
机构：
[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
来源：
INORGANIC CHEMISTRY | 1998年 / 37卷 / 21期
关键词：
D O I：
10.1021/ic9807386
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Chiral 12-metallacrown-4 complexes can now be obtained in high yield using resolved beta-phenylalanine hydroxamic acids as organic scaffolding. These new copper(II) compounds bear a striking resemblance based on size and shape to Cu(II) tetraphenylporphyrin. This suggests that metallacrowns may be useful alternatives to metalloporphyrins in future applications which require high metal densities and well-defined chiral centers.
引用
收藏
页码：5416 / +
页数：3
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