Preparation and electrochemical properties of a new organic donor bis-(hydroxymethylethylenedithio)-tetrathiafulvalene

被引：3
|
作者：
Liu, SG [1 ]
Liu, YQ [1 ]
Wu, PJ [1 ]
Li, YF [1 ]
Zhu, DB [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1997年 / 127卷
基金：
中国国家自然科学基金;
关键词：
organic electron donor; synthesis; electrochemistry;
D O I：
10.1080/10426509708040498
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Preparation and characterization of a new organic donor molecule bis(hydroxymethylethylenedithio)-tetrathiafulvalene is reported. Cyclic voltammogram (Figure 1) of the donor molecule shows two reversible redox processes in n-Bu4NBF4/DMF system at half-wave potentials of 0.64 and 0.81 V vs SCE, respectively which are higher than those of the well-known organic donor molecule bis(ethylenedithio)-tetrathiafulvalene with the corresponding values of 0.60 and 0.73 V, respectively. In addition, the pi-donor ability of some related donor molecules of the same series is compared and the effects of solvents on the half-wave potentials of the donors are studied.
引用
收藏
页码：81 / 89
页数：9
相关论文
共 50 条
  • [31] STRUCTURES AND ELECTRICAL-PROPERTIES OF SOME NEW ORGANIC CONDUCTORS DERIVED FROM THE DONOR MOLECULE TMET (S,S,S,S-BIS(DIMETHYLETHYLENEDITHIO)TETRATHIAFULVALENE)
    KARRER, A
    WALLIS, JD
    DUNITZ, JD
    HILTI, B
    MAYER, CW
    BURKLE, M
    PFEIFFER, J
    HELVETICA CHIMICA ACTA, 1987, 70 (04) : 942 - 953
  • [32] Synthesis and electrochemical properties of bis(3,4-furyldimethylthio)tetrathiafulvalene and other tetrathiafulvalene donors with eight-membered heterocycles
    Meline, RL
    Kim, IT
    Basak, S
    Elsenbaumer, RL
    SYNTHETIC METALS, 1998, 96 (03) : 205 - 207
  • [33] Synthesis, structure and electrochemical properties of two new unsymmetrical tetrathiafulvalene derivatives
    Xu, M
    Ji, Y
    Zuo, JL
    Li, YZ
    You, XZ
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2005, 42 (05) : 847 - 850
  • [34] Synthesis, photoluminescent and electrochemical properties of diacetoxyboron derivatives for bis-β-diketone linked thienothiophene
    Wang, Dan
    Wan, Yu-Peng
    Liu, Hua
    Wang, Dun-Jia
    Yin, Guo-Dong
    DYES AND PIGMENTS, 2018, 149 : 728 - 735
  • [35] Highlighting Intermolecular Contacts and Spectral Properties in a New Organic Donor-Acceptor Complex: Synthesis, Structure and Infrared Spectroscopy of MT-TCNB (MT = bis(methylenedithio)tetrathiafulvalene)
    Fisher, Steven P.
    Reinheimer, Eric W.
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2013, 43 (07) : 343 - 351
  • [36] Conducting polymer films with new organic donor MDT-TSF: preparation and properties
    Tracz, A.
    Mierczynska, A.
    Takimiya, K.
    Otsubo, T.
    Niihara, N.
    Jeszka, J. K.
    MATERIALS SCIENCE-POLAND, 2006, 24 (02): : 517 - 526
  • [37] NEW PREPARATION OF CHLOROMETHYL METHYL-ETHER FREE OF BIS-[CHLOROMETHYL] ETHER
    AMATO, JS
    KARADY, S
    SLETZINGER, M
    WEINSTOCK, LM
    SYNTHESIS-STUTTGART, 1979, (12): : 970 - 971
  • [38] ELECTROCHEMICAL PREPARATION AND PROPERTIES OF A NEW THIOCARBONATE
    JEROSCHEWSKI, P
    STRUBING, B
    BERGE, H
    ZEITSCHRIFT FUR CHEMIE, 1980, 20 (03): : 102 - 103
  • [39] Metallic polymer composites with bis(ethylenedioxy)-tetrathiafulvalene salts. Preparation-properties relationship
    Jeszka, JK
    Tracz, A
    Sroczynska, A
    Kryszewski, M
    Yamochi, H
    Horiuchi, S
    Saito, G
    Ulanski, J
    SYNTHETIC METALS, 1999, 106 (02) : 75 - 83
  • [40] New organic semiconductor based on tetrathiafulvalene and squarate radical ions:: Electrochemical synthesis and characterization
    Farnia, G
    Marcuzzi, F
    Meneghetti, M
    Sandonà, G
    ADVANCED MATERIALS, 2000, 12 (21) : 1610 - +
12345