Preparation and characterization of activated carbon produced from rice straw by (NH4)2HPO4 activation

被引：97
|
作者：
Gao, Pin [1 ]
Liu, Zhen-hong [1 ]
Xue, Gang [1 ]
Han, Bin [1 ]
Zhou, Mei-hua [1 ]
机构：
[1] Donghua Univ, Coll Environm Sci & Engn, Shanghai 201620, Peoples R China
来源：
BIORESOURCE TECHNOLOGY | 2011年 / 102卷 / 03期
关键词：
Activated carbon; Rice straw; Pretreatment protocol; (NH4)(2)HPO4; Activation;
D O I：
10.1016/j.biortech.2010.11.080
中图分类号：
S2 [农业工程];
学科分类号：
0828 ;
摘要：
Effects of different pretreatment protocols in (NH4)(2)HPO4 activation of rice straw on porous activated carbon evolution were evaluated. The pore structure, morphology and surface chemistry of obtained activated carbons were investigated by nitrogen adsorption, scanning electron microscopy and Fourier transform infrared spectroscopy. It was found that pretreatment combining impregnation with (NH4)(2)HPO4 and preoxidation could significantly affect the physicochemical properties of prepared activated carbons. The apparent surface area and total pore volume as high as 1154 m(2)/g and 0.670 cm(3)/g were obtained respectively, when combined process of impregnation followed by preoxidation at 200 degrees C and activation at 700 degrees C was carried out. Meanwhile, the activated carbon yield and maximum methylene blue adsorption capacity up to 41.14% and 129.5 mg/g were achieved, respectively. The results exhibited that (NH4)(2)HPO4 could be an effective activating agent for producing activated carbons from rice straw. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3645 / 3648
页数：4
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