Total synthesis and absolute configuration determination of (+)-subincanadine F

被引：35

作者：

Chen, Pinhong ^{[1
]}

Cao, Lidong ^{[1
]}

Tian, Wenhai ^{[1
]}

Wang, Xinfeng ^{[1
]}

Li, Chaozhong ^{[1
]}

机构：

[1] Chinese Acad Sci, Key Lab Synthet Chem Nat Subst, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 44期

基金：

中国国家自然科学基金;

关键词：

RADICAL REACTIONS; ALKALOIDS; CYCLIZATIONS; COMBINATION; ESTERS; IODIDE;

D O I：

10.1039/c0cc03428b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first asymmetric synthesis of indole alkaloid (+)-subincanadine F was successfully accomplished with the uncommon 7-endo-trig stereoselective radical cyclization as the key step and its absolute configuration was thus assigned.

引用

页码：8436 / 8438

页数：3

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