Total synthesis and absolute configuration determination of (+)-subincanadine F

被引:35
|
作者
Chen, Pinhong [1 ]
Cao, Lidong [1 ]
Tian, Wenhai [1 ]
Wang, Xinfeng [1 ]
Li, Chaozhong [1 ]
机构
[1] Chinese Acad Sci, Key Lab Synthet Chem Nat Subst, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
基金
中国国家自然科学基金;
关键词
RADICAL REACTIONS; ALKALOIDS; CYCLIZATIONS; COMBINATION; ESTERS; IODIDE;
D O I
10.1039/c0cc03428b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first asymmetric synthesis of indole alkaloid (+)-subincanadine F was successfully accomplished with the uncommon 7-endo-trig stereoselective radical cyclization as the key step and its absolute configuration was thus assigned.
引用
收藏
页码:8436 / 8438
页数:3
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