Dinuclear Eu+3 and Tb+3 complexes based on 1,2,4,5-tetrakis(diphenylphosphinyl)-benzene: Synthesis and luminescence properties

被引：3
|
作者：
Brel, V. K. [1 ]
Fedorov, Yu. V. [1 ]
Vologzhanina, A. V. [1 ]
Dorovatovskii, P. V. [2 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
[2] Natl Res Ctr Kurchatov Inst, Moscow 123182, Russia
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2022年 / 146卷
基金：
俄罗斯科学基金会;
关键词：
Complex Eu(III); Complex Tb(III); Luminescence; DNA-BINDING; LN(III) COMPLEXES; CRYSTAL-STRUCTURE; PO BOND; LANTHANIDE; COORDINATION; POLYMORPHS; LIGANDS; PROBES;
D O I：
10.1016/j.inoche.2022.110181
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A dinuclear Eu(III) and Tb(III) trinitrate complexes, {[Eu(H2O)(NO3)3]2L}center dot H2O (1) and {[Tb(CH3OH)(NO3)3]2L} (2), has been synthesized by the reaction of 1,2,4,5-tetrakis(diphenylphosphino)benzene (L) with 2 equiv. of Eu(NO3)3 center dot 6H2O and Tb(NO3)3 center dot 5H2O. Both complexes were structurally characterized and their photo physical properties were studied. Complex {[Eu(H20)(NO3)3]2L}center dot H2O strongly emits light in the characteristic red region and complex {[Tb(CH3OH)(NO3)3]2L} strongly emits light in the green region. The luminescence quantum yields for both complexes are quite high.
引用
收藏
页数：5
相关论文
共 50 条
  • [31] Hydrothermal synthesis and luminescence properties of KCaY (PO4)2: Tb3+, Eu3+ phosphor
    Li, Z.-Q. (fgs@hbu.edu.cn), 1600, Editorial Office of Chinese Optics (33):
  • [32] Interactions in crystals .111. Crystallization and structure determination of donor/acceptor complexes between 1,2,4,5-tetrakis(alkylthio)benzene derivatives and bromine or iodine
    Bock, H
    Rauschenbach, A
    Nather, C
    Kleine, M
    Havlas, Z
    LIEBIGS ANNALEN, 1996, (12): : 2185 - 2194
  • [33] ELECTRON-DONOR ACCEPTOR COMPOUNDS .42. 1,2,4,5-TETRAKIS(DIMETHYLAMINO)BENZENE, A NEW ELECTRON-DONOR WITH UNUSUAL PROPERTIES
    ELBL, K
    KRIEGER, C
    STAAB, HA
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (11): : 1023 - 1024
  • [34] LUMINESCENCE PROPERTIES OF EU3+ AND TB3+ COMPLEXES OF BRANCHED MACROCYCLIC LIGANDS CONTAINING 4 2,2'-BIPYRIDINE UNITS
    BALZANI, V
    LEHN, JM
    VANDELOOSDRECHT, J
    MECATI, A
    SABBATINI, N
    ZIESSEL, R
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (02): : 190 - 191
  • [35] Synthesis and Luminescence Properties of NaSrPO4:Eu2+, Tb3+, Mn2+ for WLED
    Huang, Shan
    Chen, Yonghu
    Wei, Xiantao
    Yin, Min
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2014, 14 (06) : 4574 - 4578
  • [36] Synthesis and luminescence properties of SrMoO4:RE3+ (RE = Eu or Tb) phosphors
    Shinho Cho
    Journal of the Korean Physical Society, 2014, 64 : 1529 - 1534
  • [37] Synthesis and luminescence properties of SrMoO4:RE3+ (RE = Eu or Tb) phosphors
    Cho, Shinho
    JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 2014, 64 (10) : 1529 - 1534
  • [38] Synthesis and characterization of the new carbacylamidophosphate based rare earth tetrakis-complexes NEt4[LnL4]. Effect of the ligand nitro group on luminescence of Eu3+and Tb3+.
    Horniichuk, O. Y.
    Klimov, I. S.
    Trush, V. O.
    Kariaka, N. S.
    Domasevitch, K. V.
    Dyakonenko, V. V.
    Shishkina, S. V.
    Smola, S. S.
    Rusakova, N. V.
    Amirkhanov, V. M.
    JOURNAL OF MOLECULAR STRUCTURE, 2023, 1278
  • [39] Secondary interactions in the crystal structures of three 1,2,4,5-tetrakis(bromomethyl)-3,6-bis(2-alkoxy)benzenes
    Vande Velde, Christophe M. L.
    Zeller, Matthias
    Azov, Vladimir A.
    JOURNAL OF MOLECULAR STRUCTURE, 2012, 1016 : 109 - 117
  • [40] Hydrothermal synthesis and tunable luminescence of YPO4:Eu2+/Eu3+, Tb3+nanocrystals
    Yu, Ying
    Yu, Lixin
    Peng, Kangliang
    Sun, Dandan
    Zeng, Xiaoling
    Deng, Yakun
    Zhao, Youjun
    Xu, Yinan
    CERAMICS INTERNATIONAL, 2023, 49 (17) : 29317 - 29326
12345