Bis-, tris-, and tetrakis-N-(2-nitroxyethyl) derivatives of 1,1′-[methylenebis(oxy)]bis(triaz-1-ene 2-oxides)

被引:10
|
作者
Smirnov, G. A. [1 ]
Gordeev, P. B. [1 ]
Nikitin, S. V. [1 ]
Pokhvisneva, G. V. [1 ]
Ternikova, T. V. [1 ]
Chistokhvalov, I. M. [2 ]
Luk'yanov, O. A. [1 ]
机构
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Prosp, Moscow 119991, Russia
[2] D Mendeleev Univ Chem Technol Russia, 9 Miusskaya Pl, Moscow 125047, Russia
基金
俄罗斯科学基金会;
关键词
NO donors; 1,1 '-[methylenebis(oxy)]bis(triaz-1-ene 2-oxides); 2-bromoethyl derivatives; 2-hydroxyethyl derivatives; 2-nitroxyethyl derivatives; nitrates; alkylation; nitration; nucleophilic substitution; hydrolysis; METHYLENE-BIS(1-OXY-3,3-DIALKYL-1-TRIAZENE 2-OXIDES); OXIDE; SYSTEMS; ACID;
D O I
10.1007/s11172-018-2274-5
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Synthesis of new potential NO donors in living organisms, 1,1'-[methylenebis(oxy)]bis(triaz-1-ene 2-oxides) bearing from two to four 2-nitroxyethyl groups at the nitrogen atoms was accomplished. The developed synthetic approaches involves either nucleophilic substitution of the bromine atoms of the corresponding N-2-bromoethyl derivatives of 1,1'-[methylenebis(oxy)]-bis(triaz-1-ene 2-oxides) or nitration of its 2-hydroxyethyl analogs. Some of the synthesized compounds are of interest as promising energetic materials.
引用
收藏
页码:1662 / 1670
页数:9
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