Structural, magnetic and field-driven abrupt magnetocaloric properties of La1.4-xSmxCa1.6Mn2O7 Ruddlesden-Popper manganites

被引：13
|
作者：
Kumar, Akshay [1 ]
Kumari, Kavita [2 ]
Vij, Ankush [3 ]
Kumar, Shalendra [3 ,4 ]
Shin, Minji [1 ]
Koo, Bon Heun [1 ,2 ]
机构：
[1] Changwon Natl Univ, Dept Mat Convergence & Syst Engn, Chang Won 51140, Gyeongnam, South Korea
[2] Changwon Natl Univ, Sch Mat Sci & Engn, Chang Won 51140, Gyeongnam, South Korea
[3] Univ Petr & Energy Studies, Dept Phys, Dehra Dun 248007, Uttarakhand, India
[4] King Faisal Univ, Coll Sci, Dept Phys, Al Hufuf 31982, Al Ahsa, Saudi Arabia
来源：
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2021年 / 41卷 / 14期
基金：
新加坡国家研究基金会;
关键词：
Magnetocaloric; Ruddlesden-Popper manganites; Solid-state reaction method; Heat capacity; Isothermal entropy change; ADIABATIC TEMPERATURE-CHANGE; ELECTRONIC-PROPERTIES; HEAT-CAPACITY; ENTROPY; SPIN; TRANSITION; BEHAVIOR; OXIDES; SHAPE; LA;
D O I：
10.1016/j.jeurceramsoc.2021.07.033
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Evolution in the structural, magnetic and magnetocaloric (MCE) properties for a series of samarium (Sm) doped La1.4-xSmxCa1.6Mn2O7 (0.0 <= x <= 0.4) Ruddlesden-Popper manganites prepared by using the solid-state reaction method have been investigated. Structural refinement of XRD profiles established that the MnO6 octahedral structural units were distorted upon Sm-substitution. The effect of Sm-concentration on the microstructure was also very well observed in terms of increased average grain size and absolute density. Discrepancy in MCE parameters by implementing the conventional isothermal curve method was appeared which was resolved with a separate calorimetric method. The isothermal entropy change was enhanced from 2.52 J/kgK for x = 0.0 sample up to 4.61 J/kgK and 4.2 J/kgK for x = 0.1 and x = 0.2 samples respectively. The temperature averaged entropy change (TEC) was also remarkably improved from 4.04 J/kgK up to 8.5 J/kgK and 7.77 J/kgK for the same compounds respectively.
引用
收藏
页码：7050 / 7061
页数：12
相关论文
共 50 条
  • [31] Effect of subsidiary phase on the magnetic and transport properties of Sr1.6La1.4Mn2O7
    Kim, WS
    Choi, HS
    Nam, BC
    Chi, EO
    Lee, KW
    Hur, NH
    PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2001, 185 (02): : 401 - 411
  • [32] Magnetocaloric effect in layered perovskite manganese oxide La1.4Ca1.6Mn2O7
    Zhu, H
    Song, H
    Zhang, YH
    APPLIED PHYSICS LETTERS, 2002, 81 (18) : 3416 - 3418
  • [33] Magnetocaloric and Colossal Magnetoresistance Effect in Layered Perovskite La1.4Sr1.6Mn2O7
    Han, Li'an
    Chen, Changle
    JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2010, 26 (03) : 234 - 236
  • [34] Investigating the effects of B-site Cr doping on the structural, magnetic and magnetocaloric properties of La1.4Ca1.6Mn2- x Cr x O7 (0 x 0.4) bilayer manganites
    Kumar, Akshay
    Kumari, Kavita
    Koo, Bon Heun
    FUNCTIONAL COMPOSITES AND STRUCTURES, 2021, 3 (01):
  • [35] The oxygen deficient Ruddlesden-Popper La3Ni2O7-δ (δ=0.65) phase:: Structure and properties
    Poltavets, Viktor V.
    Lokshin, Konstantin A.
    Egami, Takeshi
    Greenblatt, Martha
    MATERIALS RESEARCH BULLETIN, 2006, 41 (05) : 955 - 960
  • [36] Electrical transport and magnetic properties of the Ruddlesden-Popper phases Sr3Fe2-xRuxO7 (0≤x≤1.4)
    Lv, Zhangming
    Ruan, Keqing
    Huang, Shengli
    Wu, Huiyan
    Cao, Liezhao
    Li, Xiaoguang
    SOLID STATE COMMUNICATIONS, 2006, 140 (7-8) : 340 - 344
  • [37] Electrical and Magnetic Properties of Bilayer Manganites La1.4Sr1.6Mn1.96TE0.04O7 (TE=Mn, Fe, Ti, Nb)
    余功奇
    袁松柳
    任光明
    缪菊红
    肖循
    王永强
    Journal of Rare Earths, 2007, (04) : 439 - 443
  • [38] Magnetic, magnetocaloric properties, and critical behavior in a layered perovskite La1.4(Sr0.95Ca0.05)1.6Mn2O7
    Arwa Belkahla
    K. Cherif
    J. Dhahri
    E. K. Hlil
    Journal of Materials Science, 2016, 51 : 7636 - 7651
  • [39] The investigation of the effect of K doping on the structural, magnetic, and magnetocaloric properties of La1.4−xKxCa1.6Mn2O7 (0.0 ≤ x ≤ 0.4) double perovskite manganite
    Arıçtan Tulga Coşkun
    Selda Kılıç Çetin
    Ahmet Ekicibil
    Journal of Materials Science: Materials in Electronics, 2022, 33 : 10990 - 11001
  • [40] Magnetic, magnetocaloric properties, and critical behavior in a layered perovskite La1.4(Sr0.95Ca0.05)1.6Mn2O7
    Belkahla, Arwa
    Cherif, K.
    Dhahri, J.
    Hlil, E. K.
    JOURNAL OF MATERIALS SCIENCE, 2016, 51 (16) : 7636 - 7651
12345