Radical polymerization of 2,3-dimethyl-1,3-butadiene in coordination nanochannels

被引：23

作者：

Uemura, Takashi ^{[1
,2
]}

Nakanishi, Ryo ^{[1
]}

Mochizuki, Shuto ^{[1
]}

Murata, Yasujiro ^{[3
]}

Kitagawa, Susumu ^{[1
,4
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[2] Japan Sci & Technol Agcy, CREST, Kawaguchi, Saitama 3320012, Japan

[3] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan

[4] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sakyo Ku, Kyoto 6068501, Japan

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 48期

关键词：

METAL-ORGANIC FRAMEWORKS; ELECTRON-SPIN-RESONANCE; INCLUSION POLYMERIZATION; DEOXYCHOLIC-ACID; POLYMERS; MICROSTRUCTURE; POLYBUTADIENES; 2,3-DIMETHYLBUTADIENE; FUNCTIONALIZATION; MONOMERS;

D O I：

10.1039/c5cc01933h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Radical polymerization of unpolymerizable sterically hindered butadiene was successfully performed in the nanochannels of porous coordination polymers because of the effective suppression of unfavourable termination reactions. Microstructures of the resulting polymer could also be tuned depending on the structure of the porous hosts.

引用

页码：9892 / 9895

页数：4

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