Radical polymerization of 2,3-dimethyl-1,3-butadiene in coordination nanochannels

被引：23
|
作者：
Uemura, Takashi [1 ,2 ]
Nakanishi, Ryo [1 ]
Mochizuki, Shuto [1 ]
Murata, Yasujiro [3 ]
Kitagawa, Susumu [1 ,4 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
[2] Japan Sci & Technol Agcy, CREST, Kawaguchi, Saitama 3320012, Japan
[3] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan
[4] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sakyo Ku, Kyoto 6068501, Japan
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 48期
关键词：
METAL-ORGANIC FRAMEWORKS; ELECTRON-SPIN-RESONANCE; INCLUSION POLYMERIZATION; DEOXYCHOLIC-ACID; POLYMERS; MICROSTRUCTURE; POLYBUTADIENES; 2,3-DIMETHYLBUTADIENE; FUNCTIONALIZATION; MONOMERS;
D O I：
10.1039/c5cc01933h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Radical polymerization of unpolymerizable sterically hindered butadiene was successfully performed in the nanochannels of porous coordination polymers because of the effective suppression of unfavourable termination reactions. Microstructures of the resulting polymer could also be tuned depending on the structure of the porous hosts.
引用
收藏
页码：9892 / 9895
页数：4
相关论文
共 50 条
  • [1] COPOLYMERS OF 1,3-BUTADIENE AND 2,3-DIMETHYL-1,3-BUTADIENE
    MARVEL, CS
    WILLIAMS, JLR
    JOURNAL OF POLYMER SCIENCE, 1949, 4 (03): : 265 - 272
  • [2] ANIONIC-POLYMERIZATION OF 2,3-DIMETHYL-1,3-BUTADIENE .2. POLYMER MICROSTRUCTURE
    JENNER, G
    KHALILPOUR, A
    EUROPEAN POLYMER JOURNAL, 1976, 12 (02) : 105 - 111
  • [3] AN ABINITIO STRUCTURAL INVESTIGATION OF 1,3-BUTADIENE, ISOPRENE AND 2,3-DIMETHYL-1,3-BUTADIENE ROTAMERS
    BOCK, CW
    PANCHENKO, YN
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1989, 56 : 69 - 82
  • [4] Radiation-induced polymerization of 2,3-dimethyl-1,3-butadiene clathrate in deoxycholic acid
    Cataldo, F.
    Ursini, O.
    Ragni, P.
    Rosati, A.
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2009, 280 (01) : 99 - 106
  • [5] Radiation-induced polymerization of 2,3-dimethyl-1,3-butadiene clathrate in deoxycholic acid
    F. Cataldo
    O. Ursini
    P. Ragni
    A. Rosati
    Journal of Radioanalytical and Nuclear Chemistry, 2009, 280 : 99 - 106
  • [6] PRODUCTS AND MECHANISMS OF THE REACTIONS OF THE NITRATE RADICAL (NO3) WITH ISOPRENE, 1,3-BUTADIENE AND 2,3-DIMETHYL-1,3-BUTADIENE IN AIR
    SKOV, H
    HJORTH, J
    LOHSE, C
    JENSEN, NR
    RESTELLI, G
    ATMOSPHERIC ENVIRONMENT PART A-GENERAL TOPICS, 1992, 26 (15): : 2771 - 2783
  • [7] STRUCTURE OF CRYSTALLINE ADDUCT OF NITROSOBENZENE AND 2,3-DIMETHYL-1,3-BUTADIENE
    OIKAWA, E
    TSUBAKI, S
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1973, 46 (06) : 1819 - 1822
  • [8] VAPOR-PHASE OXIDATION OF 2,3-DIMETHYL-1,3-BUTADIENE
    SHARIPOV, AK
    KIRICHEN.YV
    MASAGUTO.RM
    PODTEREB.AA
    BEKSHENE.NM
    KHABIBUL.MF
    SHARIPOV, BG
    ZHURNAL ORGANICHESKOI KHIMII, 1971, 7 (11): : 2236 - &
  • [9] ARENECHROMIUMTRICARBONYL-CATALYZED HYDROSILYLATION OF 2,3-DIMETHYL-1,3-BUTADIENE
    AFANASOVA, OB
    ZUBAREV, YE
    SOKOLOVA, TM
    CHERNYSHEV, EA
    ZHURNAL OBSHCHEI KHIMII, 1987, 57 (08): : 1909 - 1910
  • [10] THE HOMOPOLYMERIZATION OF 2,3-DIMETHYL-1,3-BUTADIENE AND THE COPOLYMERIZATION OF 1,3-BUTADIENE/2,3-DIMETHYL-1,3-BUTADIENE USING THE CATALYST SYSTEM ALET2CL-CO(ACAC)2 - A STRUCTURAL INVESTIGATION OF THE PRODUCTS
    CABASSI, F
    ITALIA, S
    GIARRUSSO, A
    PORRI, L
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1986, 187 (04): : 913 - 921
12345