(5,5′-Dimethyl-2,2′-bipyridine-κ2N,N′)(1-naphthylacetato-κO)(1-naphthylacetato-κ2O,O′)zinc hemihydrate

被引：8
|
作者：
Ji, Li-Li [1 ]
Liu, Jian-She [1 ]
Song, Wen-Dong [2 ]
机构：
[1] Donghua Univ, Shanghai 200051, Peoples R China
[2] Guangdong Ocean Univ, Coll Sci, Zhanjiang 524088, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
D O I：
10.1107/S1600536811013353
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Zn(C12H9O2)(2)(C12H12N2)]center dot 0.5H(2)O, the water molecule lies on a twofold rotation axis. The Zn-II atom is coordinated by three O atoms from two 1-naphthylacetate ligands, one monodentate and the other asymmetric bidentate chelate, and two N atoms from a 5,5'-dimethyl-2,2'-bipyridine ligand, giving an irregular environment. In the crystal, the complex molecules are interlinked through the water molecule by O-H center dot center dot center dot O-carboxylate hydrogen bonds, together with weak C-H center dot center dot center dot O and bipyridine ring pi-pi stacking interactions [ring centroid separation = 3.761 (2) angstrom], giving a two-dimensional network structure.
引用
收藏
页码：M606 / U934
页数：13
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