Synthesis and Characterization of Monoaminophosphine, Bis(Amino) Phosphine Derivatives, and their Metal Complexes

被引：4

作者：

Sarioz, Ozlem ^{[1
]}

Oznergiz, Sena ^{[1
]}

机构：

[1] Nigde Univ, Dept Chem, Fac Sci Arts, Nigde, Turkey

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2011年 / 41卷 / 06期

关键词：

aminophosphines; complexation; oxidation; synthesis; RAY CRYSTAL-STRUCTURES; P-N BOND; MOLECULAR-STRUCTURE; COORDINATION CHEMISTRY; AMINOPHOSPHINE LIGANDS; PHENYL; MOLYBDENUM(0); PALLADIUM(II); PLATINUM(II); DIMER;

D O I：

10.1080/15533174.2011.568464

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Functionalized monoaminophosphine of the type Ph2PNR2 (1 and 3) and bis(amino) phosphine of the type PhP(NR2)(2) (2) have been synthesized by treating Ph2PCl or PhPCl2 with corresponding amines. Ligands react with aqueous hydrogen peroxide, elemental sulfur, or selenium to give the corresponding chalcogenides in good yield. The metal complexes of the aminophosphines have been obtained. All of the compounds were obtained in good yields and were characterized by IR, NMR, and microanalysis.

引用

页码：698 / 703

页数：6

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