In the present study, a mass transfer model for Type-1 facilitated transport in liquid surfactant membrane is developed by taking into consideration a size distribution of emulsion drops, and analytical solution of the model equations has been presented. The model takes into account the continuous phase and outer liquid membrane phase resistances along with diffusion through composite emulsion drop. Effort has been made to highlight the effect of the various system parameters on the extraction rate including computation of reaction front position. The results of this work are found to be in good agreement with the published experimental results on batch extraction of phenol using NaOH as internal reagent. The model would thus provide an insight of the separation mechanism involved in the mass transfer processes in this type of system.
机构:
Semnan Univ, Fac Chem Gas & Petr Engn, POB 35195-363, Semnan, IranSemnan Univ, Fac Chem Gas & Petr Engn, POB 35195-363, Semnan, Iran
Zarei, Pouria
Asl, Ali Haghighi
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Semnan Univ, Fac Chem Gas & Petr Engn, POB 35195-363, Semnan, IranSemnan Univ, Fac Chem Gas & Petr Engn, POB 35195-363, Semnan, Iran
Asl, Ali Haghighi
Torkaman, Rezvan
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Nucl Sci & Technol Res Inst, Nucl Fuel Cycle Res Sch, POB 11365-8486, Tehran, IranSemnan Univ, Fac Chem Gas & Petr Engn, POB 35195-363, Semnan, Iran
Torkaman, Rezvan
Asadollahzadeh, Mehdi
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Nucl Sci & Technol Res Inst, Nucl Fuel Cycle Res Sch, POB 11365-8486, Tehran, IranSemnan Univ, Fac Chem Gas & Petr Engn, POB 35195-363, Semnan, Iran
机构:
Univ Rouen, UMR Polymeres Biopolymeres Membranes 6522 CNRS, F-76821 Mont St Aignan, FranceUniv Rouen, UMR Polymeres Biopolymeres Membranes 6522 CNRS, F-76821 Mont St Aignan, France