Optimization of the separation and purification of Al13

被引:62
|
作者
Xu, Y
Wang, DS
Liu, H
Lu, YQ
Tang, HX
机构
[1] Chinese Acad Sci, Ecoenvironm Sci Res Ctr, SKLEAC, Beijing 100085, Peoples R China
[2] Beijing Univ Sci & Technol, Coll Chem, Beijing 100083, Peoples R China
关键词
PACL; Al-13; optimization process; purification; coagulation;
D O I
10.1016/j.colsurfa.2003.08.021
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The optimum process for the separation and purification of Al-13 was investigated in detail in this paper. The various influencing factors were discussed. The experimental results show that the concentration and basicity (B, OH/Al ratio) of polyaluminum chloride (PACl, Al/SO4 ratio, Ba/SO4] ratio and ultrasonic reaction have different roles in the separation and purification of Al-13.Moderate concentration of PACl with the basicity around 2.0 gives some benefits in the separation of Al-13. An optimization condition has then been found to obtain high purity Al-13 by involving Al/SPO4 and Ba/SO4 ratios of 1:1, and 3h ultrasonic time. Further indication on the separation of Al-13 is also discussed. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 9
页数:9
相关论文
共 50 条
  • [21] The formation mechanism of Al13 and its purification with an ethanol-acetone fractional precipitation method
    Zhao, Hua-Zhang
    Wang, Hong-Yu
    Dockko, Seok
    Zhang, Yan
    SEPARATION AND PURIFICATION TECHNOLOGY, 2011, 81 (03) : 466 - 471
  • [22] Effect of Temperature on the Degradation of Al13 Complex
    Pa Ho Hsu
    Clays and Clay Minerals, 1997, 45 : 286 - 289
  • [23] CHEMISORPTION OF O AND H ON AN AL13 CLUSTER
    PARTRIDGE, H
    BAUSCHLICHER, CW
    JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (11): : 6507 - 6510
  • [24] Stability Analysis of Al13 Hydroxyl Complexion and Al13- Cluster
    Lv, J. X.
    Jia, B. J.
    Xie, G. H.
    Zhang, L.
    Zhou, L. Y.
    Wang, S. F.
    Li, J. M.
    Cui, Y.
    ITESS: 2008 PROCEEDINGS OF INFORMATION TECHNOLOGY AND ENVIRONMENTAL SYSTEM SCIENCES, PT 1, 2008, : 14 - 18
  • [25] Formation of Al13I-:: Evidence for the superhalogen character of Al13
    Bergeron, DE
    Castleman, AW
    Morisato, T
    Khanna, SN
    SCIENCE, 2004, 304 (5667) : 84 - 87
  • [26] Preparation and characterization of polynuclear Al13 species
    Luo, MB
    Wang, CY
    Liu, SJ
    Bi, SP
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2004, 20 (01) : 69 - 73
  • [27] Energetics of Al13 Keggin cluster compounds
    Armstrong, Christopher R.
    Casey, William H.
    Navrotsky, Alexandra
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2011, 108 (36) : 14775 - 14779
  • [28] EVIDENCE FOR A HYDROXYALUMINUM POLYMER (AL13) IN SYNAPTOSOMES
    RAO, GV
    RAO, KSJ
    FEBS LETTERS, 1992, 311 (01) : 49 - 50
  • [29] Intercalation of both CTMAB and Al13 into montmorillonite
    Zhu, Runliang
    Wang, Tong
    Ge, Fei
    Chen, Wangxiang
    You, Zhimin
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 335 (01) : 77 - 83
  • [30] Separation and purification of nano-Al13 by UF method
    Huang, L
    Wang, DS
    Tang, HX
    Wang, SF
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2006, 275 (1-3) : 200 - 208