Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site

被引：60

作者：

Xu, Fenfen ^{[1
]}

Tard, Cedric ^{[2
]}

Wang, Xiufeng ^{[1
]}

Ibrahim, Saad K. ^{[2
]}

Hughes, David L. ^{[2
]}

Zhong, Wei ^{[1
]}

Zeng, Xirui ^{[3
]}

Luo, Qiuyan ^{[3
]}

Liu, Xiaoming ^{[1
]}

Pickett, Christopher J. ^{[2
]}

机构：

[1] Nanchang Univ, Dept Chem, Nanchang 330031, Peoples R China

[2] Univ E Anglia, Sch Chem Sci & Pharm, Norwich NR4 7TJ, Norfolk, England

[3] Jinggangshan Univ, Sch Chem & Chem Engn, Jian 343000, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 05期

关键词：

D O I：

10.1039/b712805c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon monoxide binding by displacement of a pendant hemi-labile ligand at a di-iron site can be substantially 'switched-on' via a ligand protonation pathway which is competitive with metal-metal bond protonation.

引用

页码：606 / 608

页数：3

共 36 条

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[36] STEPWISE SYNTHESIS OF TROPONE FROM ETHYLENE AND CARBON-MONOXIDE AT A DI-IRON CENTER - CRYSTAL-STRUCTURE OF [FE2(CO)4(MU-C6H6CO)(MU-PH2PCH2PPH2)]
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