Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site

被引:60
|
作者
Xu, Fenfen [1 ]
Tard, Cedric [2 ]
Wang, Xiufeng [1 ]
Ibrahim, Saad K. [2 ]
Hughes, David L. [2 ]
Zhong, Wei [1 ]
Zeng, Xirui [3 ]
Luo, Qiuyan [3 ]
Liu, Xiaoming [1 ]
Pickett, Christopher J. [2 ]
机构
[1] Nanchang Univ, Dept Chem, Nanchang 330031, Peoples R China
[2] Univ E Anglia, Sch Chem Sci & Pharm, Norwich NR4 7TJ, Norfolk, England
[3] Jinggangshan Univ, Sch Chem & Chem Engn, Jian 343000, Peoples R China
关键词
D O I
10.1039/b712805c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Carbon monoxide binding by displacement of a pendant hemi-labile ligand at a di-iron site can be substantially 'switched-on' via a ligand protonation pathway which is competitive with metal-metal bond protonation.
引用
收藏
页码:606 / 608
页数:3
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