On the Role of CO2 in NHC-Catalyzed Oxidation of Aldehydes

被引：97
|
作者：
Chiang, Pei-Chen
Bode, Jeffrey W. [1 ]
机构：
[1] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA
来源：
ORGANIC LETTERS | 2011年 / 13卷 / 09期
关键词：
N-HETEROCYCLIC CARBENE; ENVIRONMENTALLY BENIGN OXIDATION; CARBON-DIOXIDE; AROMATIC-ALDEHYDES; BOND-CLEAVAGE; CONVERSION; DECARBOXYLATION; ORGANOCATALYSTS; CARBOXYLATES; MECHANISM;
D O I：
10.1021/ol2006538
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
NHC-catalyzed oxidations using carbon dioxide as the stoichiometric oxidant have been carefully investigated. These studies support a secondary role of CO2 in suppressing side reactions and exogenous oxygen as the actual oxidant.
引用
收藏
页码：2422 / 2425
页数：4
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