Transmission FT-IR Study on the Adsorption Imd Reactions of Lactic Acid and Poly(lactic acid) on TiO2

被引：52

作者：

Chen, Yi-Kwan ^{[1
]}

Lin, Yu-Feng ^{[1
]}

Peng, Zih-Wei ^{[1
]}

Lin, Jong-Liang ^{[1
]}

机构：

[1] Natl Cheng Kung Univ, Dept Chem, Tainan 70101, Taiwan

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2010年 / 114卷 / 41期

关键词：

ACRYLIC-ACID; CONVERSION; SILICA; DECOMPOSITION; CATALYSTS; SURFACES; ALCOHOLS; SPECTRA; OXIDE;

D O I：

10.1021/jp105581t

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In situ Fourier transform infrared spectroscopy has been employed to investigate the adsorption and thermal decomposition of lactic acid and poly(lactic acid) on TiO2 with and without O-2,O- Lactic acid dissociates primarily by deprotonation of COOII to form lactate (CH3CH(OH)COO) on TiO2 and by O-H (alcohol's functional group) bond scission to form 2-oxy-propionic acid (CH3CH(O)COOH). As the surface temperature is raised higher than similar to 250 degrees C in a vacuum, propionate is formed with minor acetate. In contrast, only acetate is formed with simultaneous CO2 evolution in the lactic acid decomposition in the presence of O. No other products, such as acrylate from dehydration or pyruvate from oxidation of the 011 group, are found. Poly(lactic acid) can dissociate by breaking the ester linkage, forming carboxylate species, on TiO2 at 30 degrees C. Poly(lactic acid) has the same high-temperature reaction products as those of lactic acid on TiO2. Besides, poly(lactic acid) on TiO2 irradiated at similar to 320 tun in the presence of O-2 is subjected to photodecomposition, generating CO, and acetate. Possible mechanisms for decomposition of lactic acid and poly(lactic acid) on TiO2 are proposed.

引用

页码：17720 / 17727

页数：8

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