Kinetics of silicalite-1 crystallization

被引：0
|
作者：
Rimer, J. D. [1 ]
Vlachos, D. G. [1 ]
Lobo, R. F. [1 ]
机构：
[1] Univ Delaware, Ctr Catalyt Sci & Technol, Dept Chem Engn, Newark, DE 19716 USA
来源：
FROM ZEOLITES TO POROUS MOF MATERIALS: THE 40TH ANNIVERSARY OF INTERNATIONAL ZEOLITE CONFERENCE, PROCEEDINGS OF THE 15TH INTERNATIONAL ZEOLITE CONFERENCE | 2007年 / 170卷
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D O I：
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中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Growth rates of silicalite-1 in combination with thermodynamic aspects of the aqueous chemistry of silica are used to evaluate two zeolite growth models. Analysis of a nanoparticle growth model indicates that, in its current state, the model does not adequately predict the effect of ionic strength and pH on growth rates. Preliminary studies of a monomer addition model based on solution chemistry, indicate the model is capable of quantitatively calculating growth rates as a function of temperature, pH, silica concentration, and ionic strength.
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页码：133 / 144
页数：12
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