Generalization of data on solvent effect on formation of charge-transfer complexes using linear multiparameter equations

被引：1
|
作者：
Makitra, RG [1 ]
Polyuzhin, IP
Shevchuk, IP
机构：
[1] Natl Acad Sci Ukraine, Div Phys Chem & Technol Fossil Fuels, LV Pisarzhevsky Phys Chem Inst, Lvov, Ukraine
[2] Lvovskaya Polytech Natl Univ, Lvov, Ukraine
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2005年 / 75卷 / 02期
关键词：
Correlation Analysis; Equilibrium Constant; Solvent Polarity; Solvent Effect; Solvent Property;
D O I：
10.1007/s11176-005-0194-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The correlation analysis of data on the equilibrium constants of formation of various charge-transfer complexes (K-e) in various solvents shows that the solvent polarity alone does not provide sufficiently reliable description of the process. An adequate correlation between K. and solvent properties can be obtained only with combined consideration of the capability of solvents for specific and nonspecific solvation.
引用
收藏
页码：177 / 180
页数：4
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