Blended lithium ion conducting polymer electrolytes based on boroxine polymers

被引：20

作者：

Yang, Y

Inoue, T

Fujinami, T

Mehta, MA ^{[1
]}

机构：

[1] Shizuoka Univ, Fac Engn, Dept Mat Sci, Hamamatsu, Shizuoka 4328561, Japan

[2] Genesis Res Inst, Nishi Ku, Nagoya, Aichi 4510051, Japan

来源：

SOLID STATE IONICS | 2001年 / 140卷 / 3-4期

关键词：

polymer electrolyte; ionic conductivity; lithium ion conductor; boroxine ring;

D O I：

10.1016/S0167-2738(01)00820-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new series of blended polymer electrolytes based on a boroxine polymer (BP) with poly(ethylene oxide) (PEO), an ethylene oxide-propylene oxide copolymer or poly(methyl methacrylate) were prepared. Good room temperature mechanical properties were exhibited by electrolytes containing in excess of 30% PEG. Cationic transference number measurements indicated that a slight improvement in lithium ion conductivity could be achieved by using a mixture of LiCF3SO3 and LiN(CF3SO2)(2) as the electrolyte salt. Electrolytes incorporating significant proportions of BP exhibited reduced lithium-polymer electrolyte interfacial resistance. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：353 / 359

页数：7

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