Regioselective addition of PRPh2 to the Cα atom of the diphenylallenylidene ligand of [Ru(η5-C5H5) (C=C=CPh2)(CO)(PPri3)]BF4

被引：60

作者：

Esteruelas, MA ^{[1
]}

Gómez, AV ^{[1
]}

López, AM ^{[1
]}

Modrego, J ^{[1
]}

Oñate, E ^{[1
]}

机构：

[1] Univ Zaragoza, Inst Ciencia Mat Aragon, Dept Quim Inorgan, CSIC, E-50009 Zaragoza, Spain

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 24期

关键词：

D O I：

10.1021/om980577d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The allenylidene ligand of [Ru(eta(5)-C5H5){C = C=CPh2}(CO)(PPr3i)]BF4 adds PHPh2, PMePh2, and PPh3 selectively at the C-alpha atom, whereas OH- and [OMe](-) are added at the C-gamma atom.

引用

页码：5434 / 5436

页数：3

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