Regioselective addition of PRPh2 to the Cα atom of the diphenylallenylidene ligand of [Ru(η5-C5H5) (C=C=CPh2)(CO)(PPri3)]BF4

被引：60
|
作者：
Esteruelas, MA [1 ]
Gómez, AV [1 ]
López, AM [1 ]
Modrego, J [1 ]
Oñate, E [1 ]
机构：
[1] Univ Zaragoza, Inst Ciencia Mat Aragon, Dept Quim Inorgan, CSIC, E-50009 Zaragoza, Spain
来源：
ORGANOMETALLICS | 1998年 / 17卷 / 24期
关键词：
D O I：
10.1021/om980577d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The allenylidene ligand of [Ru(eta(5)-C5H5){C = C=CPh2}(CO)(PPr3i)]BF4 adds PHPh2, PMePh2, and PPh3 selectively at the C-alpha atom, whereas OH- and [OMe](-) are added at the C-gamma atom.
引用
收藏
页码：5434 / 5436
页数：3
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