Solid phase extraction of uranium on a new brush type graft copolymer and spectrophotometric determination of its in water samples

被引:4
|
作者
Tuzen, Mustafa [1 ,2 ]
Bagda, Esra [3 ]
Hazer, Baki [4 ]
机构
[1] Gaziosmanpasa Univ, Dept Chem, TR-60250 Tokat, Turkey
[2] King Fahd Univ Petr & Minerals, Res Inst, Ctr Environm & Water, Dhahran 31261, Saudi Arabia
[3] Cumhuriyet Univ, Fac Pharm, TR-58140 Sivas, Turkey
[4] Bulent Ecevit Univ, Dept Chem, TR-67100 Zonguldak, Turkey
关键词
Solid phase extraction; Pyrocatechol violet; Uranium; Water samples; Spectrophotometer; LIQUID-LIQUID MICROEXTRACTION; ALPHA-PARTICLE SPECTROMETRY; ULTRA-TRACE AMOUNTS; RADIOMETRIC DETERMINATION; SEQUENTIAL DETERMINATION; ENVIRONMENTAL-SAMPLES; ICP-MS; PRECONCENTRATION; SEPARATION; THORIUM;
D O I
10.1007/s10967-016-4949-4
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A new versatile solid phase extraction and spectrophotometric determination of uranium (VI) was proposed with using poly(caprolactone-b-vinyl benzyl chloride-g-dimethyl amino ethyl methacrylate), poly(CL-b-VB-g-DMAEMA), amphiphilic brush type block/graft copolymer. The method is based on the adsorption of uranium(VI)-pyrocatechol violet complex on surface on the adsorbent. The parameters such as pH, amount of ligand and copolymer, sample volume were optimized. Detection limit, preconcentration factor and relative standard deviation were found as 0.45 A mu g L-1, 100 and 3.8 %, respectively. Adsorption capacity of the polymer for uranium(VI) was found 52 mg g(-1). The method was applied to different water samples and standard reference materials.
引用
收藏
页码:1255 / 1263
页数:9
相关论文
共 50 条
  • [21] Solid phase extraction and spectrophotometric determination of vanadium
    Zhang, CM
    Hu, QF
    Gu, K
    Yang, GY
    Yin, JY
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2004, 43 (12): : 2590 - 2594
  • [22] Resistance, bioaccumulation and solid phase extraction of uranium (VI) by Bacillus vallismortis and its UV-vis spectrophotometric determination
    Ozdemir, Sadin
    Oduncu, M. Kadir
    Kilinc, Ersin
    Soylak, Mustafa
    JOURNAL OF ENVIRONMENTAL RADIOACTIVITY, 2017, 171 : 217 - 225
  • [23] Multisyringe flow injection spectrophotometric determination of uranium in water samples
    Jorge L. Guzmán Mar
    Leticia López Martínez
    Pedro L. López de Alba
    Nancy Ornelas Soto
    Víctor Cerdà Martín
    Journal of Radioanalytical and Nuclear Chemistry, 2009, 281 : 433 - 439
  • [24] Multisyringe flow injection spectrophotometric determination of uranium in water samples
    Guzman Mar, Jorge L.
    Lopez Martinez, Leticia
    Lopez de Alba, Pedro L.
    Ornelas Soto, Nancy
    Cerda Martin, Victor
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2009, 281 (03) : 433 - 439
  • [25] Solid-phase extraction and spectrophotometric determination of trace amounts of mercury in natural samples
    Kara, D
    Tekin, N
    MICROCHIMICA ACTA, 2005, 149 (3-4) : 193 - 198
  • [26] Solid-Phase Extraction and Spectrophotometric Determination of Trace Amounts of Mercury in Natural Samples
    Derya Kara
    Nalan Tekin
    Microchimica Acta, 2005, 149 : 193 - 198
  • [27] A new functionalized resin and its application in flame atomic absorption spectrophotometric determination of trace amounts of heavy metal ions after solid phase extraction in water samples
    Khazaeli, Sadegh
    Nezamabadi, Nadia
    Rabani, Mohammad
    Panahi, Homayon Ahmad
    MICROCHEMICAL JOURNAL, 2013, 106 : 147 - 153
  • [28] Electromembrane extraction and spectrophotometric determination of As(V) in water samples
    Kamyabi, Mohammad Ali
    Aghaei, Ali
    FOOD CHEMISTRY, 2016, 212 : 65 - 71
  • [29] Solid phase extraction and spectrophotometric determination of iron in water with 8-hydroxyquinadine
    Chen, JH
    Hu, QF
    Yang, GY
    Yin, JY
    CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 2003, 31 (07) : 853 - 855
  • [30] In situ preconcentration method for iron(II) in environmental water samples using solid phase extraction followed by spectrophotometric determination
    Okumura, M
    Seike, Y
    Fujinaga, K
    Hirao, K
    ANALYTICAL SCIENCES, 1997, 13 (02) : 231 - 235