Selective oxidation of organic compounds using pyridinium-1-sulfonate fluorochromate, C5H5NSO3H[CrO3F] (PSFC)

被引：20
|
作者：
Bekhradnia, Ahmad R. [1 ]
Zahir, Forohe [1 ]
Arshadi, Sattar [2 ]
机构：
[1] Mazandaran Univ Med Sci, Dept Med Chem, Sari, Mazandaran, Iran
[2] Univ Payame Noor, Dept Chem, Behshahr, Iran
来源：
MONATSHEFTE FUR CHEMIE | 2008年 / 139卷 / 05期
关键词：
oxidation; oxidizing reagent; pyridinium-1-sulfonate fluorochromate; carbonyl compounds;
D O I：
10.1007/s00706-007-0720-4
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Efficient selective oxidation of primary, secondary, and benzylic alcohols to the corresponding carbonyl compounds by a new chromium oxidizing reagent, pyridinium-1-sulfonate fluorochromate, C5H5NSO3H [CrO3F] (PSFC) is reported. Various cholesterol derivatives were easily converted to related oxocholesterol from allylic oxidation at lower temperature in comparison to other general oxidants. This oxidation procedure is simple and affords good yields.
引用
收藏
页码：521 / 523
页数：3
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