Oxidant-Induced Azolation of Electron-Rich Phenol Derivatives

被引：15

作者：

Wang, Xiaoyu ^{[1
]}

Wang, Shengchun ^{[2
]}

Gao, Yiming ^{[2
]}

Sun, He ^{[2
]}

Liang, Xing'an ^{[2
]}

Bu, Faxiang ^{[2
]}

Abdelilah, Takfaoui ^{[2
]}

Lei, Aiwen ^{[1
,2
]}

机构：

[1] Jiangxi Normal Univ, Natl Res Ctr Carbohydrate Synth, Nanchang 330022, Jiangxi, Peoples R China

[2] Wuhan Univ, Inst Adv Studies IAS, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

来源：

ORGANIC LETTERS | 2020年 / 22卷 / 14期

基金：

中国国家自然科学基金;

关键词：

C-H AMINATION; CATALYZED ARYLATION; PALLADIUM; FUNCTIONALIZATION;

D O I：

10.1021/acs.orglett.0c01796

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Since N-arylazoles are widely present in natural products, pharmaceuticals, and functional materials, it is important to develop a simple and efficient synthetic method for the synthesis of N-arylazoles. Herein, an oxidant-induced intermolecular azolation of phenol derivatives was demonstrated under catalyst-free condition. Both monoazolation and diazolation of phenols can be successfully achieved via this practical and powerful method.

引用

页码：5429 / 5433

页数：5

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