Chiral Sensor for Enantiodiscrimination of Varied Acids

被引：46

作者：

Huang, Huayin ^{[1
]}

Bian, Guangling ^{[1
]}

Zong, Hua ^{[1
]}

Wang, Yabai ^{[1
]}

Yang, Shiwei ^{[1
]}

Yue, Huifeng ^{[1
]}

Song, Ling ^{[1
]}

Fan, Hongjun ^{[2
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

来源：

ORGANIC LETTERS | 2016年 / 18卷 / 11期

关键词：

ALPHA-AMINO-ACIDS; INDICATOR-DISPLACEMENT ASSAYS; SOLVATING AGENTS; ENANTIOMERIC EXCESS; CARBOXYLIC-ACIDS; ABSOLUTE-CONFIGURATION; SHIFT-REAGENTS; HYDROXY-ACIDS; NMR ENANTIODISCRIMINATION; DISCRIMINATION;

D O I：

10.1021/acs.orglett.6b00088

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A chiral thiophosphoroamide 4 derived from (1R,2R)-1,2-diaminocyclohexane is used as a highly effective chiral sensor for the chiral recognition of varied acids via ion-pairing and hydrogen-bonding interactions using H-1, F-19 and P-31 NMR.

引用

页码：2524 / 2527

页数：4

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