Chiral Sensor for Enantiodiscrimination of Varied Acids

被引：46
|
作者：
Huang, Huayin [1 ]
Bian, Guangling [1 ]
Zong, Hua [1 ]
Wang, Yabai [1 ]
Yang, Shiwei [1 ]
Yue, Huifeng [1 ]
Song, Ling [1 ]
Fan, Hongjun [2 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
来源：
ORGANIC LETTERS | 2016年 / 18卷 / 11期
关键词：
ALPHA-AMINO-ACIDS; INDICATOR-DISPLACEMENT ASSAYS; SOLVATING AGENTS; ENANTIOMERIC EXCESS; CARBOXYLIC-ACIDS; ABSOLUTE-CONFIGURATION; SHIFT-REAGENTS; HYDROXY-ACIDS; NMR ENANTIODISCRIMINATION; DISCRIMINATION;
D O I：
10.1021/acs.orglett.6b00088
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A chiral thiophosphoroamide 4 derived from (1R,2R)-1,2-diaminocyclohexane is used as a highly effective chiral sensor for the chiral recognition of varied acids via ion-pairing and hydrogen-bonding interactions using H-1, F-19 and P-31 NMR.
引用
收藏
页码：2524 / 2527
页数：4
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