A Novel Mn(II) Coordination Polymer Based on Carboxylate and Tris[4-(1Himidazol-1-yl)-phenyl]amine Coligands With a Rare hms Topology: Solvothermal Synthesis, Crystal Structure, and Luminescent Property

被引：3

作者：

Yu, Zhiying ^{[1
]}

机构：

[1] Weihai Vocat Coll, Dept Biol Chem Engn, Weihai 264210, Shandong, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2016年 / 46卷 / 10期

关键词：

Mn(II); crystal structure; luminescence; METAL-ORGANIC FRAMEWORKS; SUBSTITUTE GROUP; CADMIUM(II); LIGAND; NETWORK; ACID;

D O I：

10.1080/15533174.2015.1136960

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new three-dimensional coordination polymer [Mn(BPDC) (TIPA)]center dot DMF center dot H2O (1) (H2BPDC = biphenyl-3,4'-dicarboxylate, TIPA = tris[4-(1H-imidazol-1-yl)-phenyl]amine and DMF = N, N-dimethylformamide) was solvothermal synthesized by the assembly of Mn2+ ion, H2BPDC and TIPA, respectively. The title complex [Mn(BPDC) (TIPA)]center dot DMF center dot H2O (1) was characterized by IR, elemental analysis, X-ray powder diffraction, and single-crystal X-ray diffraction. Structure analysis reveals that complex 1 display a 3,5-connected twofold interpenetrated hms topology. Moreover, the luminescent property for complex 1 is investigated at room temperature.

引用

页码：1495 / 1498

页数：4

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