Ultra-uniform CuO/Cu in nitrogen-doped carbon nanofibers as a stable anode for Li-ion batteries

被引:60
|
作者
Zhang, Hang [1 ]
Zhang, Guanhua [2 ]
Li, Zhiqin [2 ]
Qu, Ke [3 ]
Wang, Lei [2 ]
Zeng, Wei [1 ]
Zhang, Qingfeng [2 ]
Duan, Huigao [2 ]
机构
[1] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China
[2] Hunan Univ, Minist Educ, Key Lab Micronano Optoelect Devices, Sch Phys & Elect, Changsha 410082, Hunan, Peoples R China
[3] Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Peoples R China
基金
中国国家自然科学基金;
关键词
HIGH-PERFORMANCE ANODE; POROUS CARBON; ELECTROCHEMICAL PROPERTIES; NEGATIVE-ELECTRODE; EXCELLENT ANODE; LITHIUM; NANOPARTICLES; GRAPHENE; NANOSTRUCTURES; NANOTUBES;
D O I
10.1039/c6ta02875f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Developing advanced anode materials is crucial to further enhance the performance of lithium-ion batteries for electrochemical energy storage. Metal oxides embedded in a carbonaceous matrix are supposed to be promising candidates as anode materials due to their high specific capacity and excellent stability. Herein, we report a CuO/Cu-based carbonaceous nanocomposite system which was used as an anode material for high-performance lithium-ion batteries via an efficient synergistic effect. With an improved fabrication strategy, the CuO/Cu could be ultra-uniformly dispersed in nitrogen-doped carbon nanofibers. Benefiting from the in situ pyrolysis of Cu salts with improved structural stability and conductivity, the hybrid nanofiber electrode showed a specific capacity of 572.0 mA h g(-1) and steady cycling performance over 500 cycles at a constant current density of 0.5 A g(-1).
引用
收藏
页码:10585 / 10592
页数:8
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