Cyrene: a bio-based novel and sustainable solvent for organic synthesis

被引：31
|
作者：
Stini, Naya A. [1 ,2 ]
Gkizis, Petros L. [1 ,2 ]
Kokotos, Christoforos G. [1 ,2 ]
机构：
[1] Natl & Kapodistrian Univ Athens, Dept Chem, Lab Organ Chem, Athens 15771, Greece
[2] Natl & Kapodistrian Univ Athens, Ctr Excellence Drug Design & Discovery, Athens 15771, Greece
来源：
GREEN CHEMISTRY | 2022年 / 24卷 / 17期
关键词：
DIHYDROLEVOGLUCOSENONE CYRENE; ALDOL CONDENSATION; GREEN SOLVENT; LEVOGLUCOSENONE; PYROLYSIS; HYDROGENATION; CELLULOSE; IDENTIFICATION; DERIVATIVES; AMINES;
D O I：
10.1039/d2gc02332f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dihydrolevoclucosenone (Cyrene is its market name) is a biomass-derived solvent that can be produced in only two steps from biomass, while being biodegradable, non-mutagenic and non-toxic. Its "green" profile combined with its physical properties makes Cyrene a plausible substitute for a number of widely used toxic organic solvents. The first attempt to assess Cyrene as a solvent dates back to 2014 and since then, numerous research groups have opted for this promising alternative. Cyrene has successfully been employed as a solvent in materials chemistry, peptide chemistry, organic synthesis and many more research fields, which are going to be discussed in the context of this review.
引用
收藏
页码：6435 / 6449
页数：15
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