First selenide-centered CuI8 cubic clusters containing dialkyl diselenophosphate ligands.: X-ray structure of {Cu8(μ8-Se)[Se2P(OPri)2]6}

被引：49

作者：

Liu, CW

Chen, HC

Wang, JC ^{[1
]}

Keng, TC

机构：

[1] Chung Yuan Christian Univ, Dept Chem, Chungli 320, Taiwan

[2] Soochow Univ, Dept Chem, Taipei 11102, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 17期

关键词：

D O I：

10.1039/a804852e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Cu-8(mu(8)-Se)[Se2P(OPri)(2)](6)}, the first discrete Cu-8(I) cubane in which each face of the cube is bridged by a diselenophosphate ligand and has an interstitial selenide ion (Se2-), is reported.

引用

页码：1831 / 1832

页数：2

共 34 条

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[32] SYNTHESIS, STRUCTURE, AND PROPERTIES OF CLUSTER COMPOUNDS WITH DEUTERIUM-PENICILLAMINE CONTAINING CUI, CUII, AGI, NIII, AND PDII - X-RAY STRUCTURE OF PENTAKIS(HEXAAMMINECOBALT(III)) TRIS[MU-8-CHLORO-OCTAHEDRO-HEXAKIS[MU-4-[CIS-BIS(DEUTERIUM-PENCILLAMINATO(2-)-N,S)NICKEL(II)]-S,S']-CUBO-OCTAARGENTATE(I)]-NORMAL-WATER, [CO(NH3)6]5[AGI8NIII6(SC(CH3)2CH(NH2)COO)12CL]3.APPROXIMATELY197H2OS[
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[33] HYDRIDO HETEROBIMETALLIC BIS(DIPHENYLPHOSPHINO)METHANE-BRIDGED RU-RH COMPLEXES - ACTIVATION OF A P-C BOND OF BIS(DIPHENYLPHOSPHINO)METHANE TO GIVE A HETEROBIMETALLIC RU-RH COMPLEX CONTAINING A TRANS-HYDRIDOPHENYLRUTHENIUM MOIETY - X-RAY CRYSTAL-STRUCTURE OF RURHH(C6H5)(C8H12)[C6H5PCH2(C6H5)2]-[(C6H5)2PCH2P(C6H5)2].0.5C6H5CH3B
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[34] HOMOGENEOUS CATALYSIS ON METAL-CLUSTERS - THE ISOMERIZATION AND SELECTIVE HYDROGENATION OF DIENES, ALKENES, AND ALKYNES IN THE PRESENCE OF [(ETA-C5H5)NIOS3(MU-H)3(CO)9] AND [(ETA-C5H5)NIOS3(MU-H)3(CO)8L] [L = PPH2H OR P(C6H4ME-O)3] - SPECTROSCOPIC IDENTIFICATION OF THE REACTION INTERMEDIATES AND X-RAY STRUCTURE OF [OS3(MU-H)(CO)9(MECCHCME)]D
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JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (01): : 23 - 30

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