Molecular cocrystals of carboxylic acids.: XXXIII -: The crystal structure of the 1:1 adduct of indole-2-carboxylic acid with 5-nitroquinoline

被引：10

作者：

Lynch, DE ^{[1
]}

Mistry, N

Smith, G

Byriel, KA

Kennard, CHL

机构：

[1] Coventry Univ, Sch Nat & Environm Sci, Coventry CV1 5FB, W Midlands, England

[2] Queensland Univ Technol, Sch Phys Sci, Brisbane, Qld 4001, Australia

[3] Univ Queensland, Dept Chem, Brisbane, Qld 4072, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1998年 / 51卷 / 09期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1071/C98099

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molecular adducts of indole-3-acetic acid (iaa) and indole-2-carboxylic acid (ica) with 5-nitroquinoline (nq), [(iaa)(nq)(2)] (1) and [(ica)(nq)] (2), have been prepared and characterized by X-ray diffraction and spectroscopic methods. Both examples involve charge transfer as well as a network of hydrogen-bonding interactions. Thin films of compound (2), and other similar adduct complexes of ica, can be prepared by thermal evaporation techniques and in this form exhibit a weak second-order non-linear optical signal. However, these films display poor optical quality and, without improvement, are not suitable for any potential non-linear optical applications.

引用

页码：813 / 818

页数：6

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