Transfer hydrogenation of unsaturated bonds in the absence of base additives catalyzed by a cobalt-based heterogeneous catalyst

被引：99

作者：

Long, Jilan ^{[1
]}

Zhou, Ying ^{[1
]}

Li, Yingwei ^{[1
]}

机构：

[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 12期

基金：

中国国家自然科学基金;

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; METAL-ORGANIC FRAMEWORKS; PRIMARY AMINES; HIGHLY EFFICIENT; IRON(II) COMPLEXES; ENANTIOSELECTIVE SYNTHESIS; PNNP LIGAND; C=N BONDS; KETONES; REDUCTION;

D O I：

10.1039/c4cc08946d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel non-noble Co@C-N catalytic system has been developed for catalytic transfer hydrogenation reactions. Co@C-N was found to be highly active and selective in the hydrogenation of a variety of unsaturated bonds with isopropanol in the absence of base additives.

引用

页码：2331 / 2334

页数：4

共 46 条

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