Oxidative dehydrogenation of ethane and propane: How far from commercial implementation?

被引：849

作者：

Cavani, F. ^{[1
]}

Ballarini, N. ^{[1
]}

Cericola, A. ^{[1
]}

机构：

[1] Alma Mater Studiorum Univ Bologna, Dipartimento Chim Ind & Mat, I-40136 Bologna, Italy

来源：

CATALYSIS TODAY | 2007年 / 127卷 / 1-4期

关键词：

oxidative dehydrogenation; olefins production; propane; ethane; reactor configurations;

D O I：

10.1016/j.cattod.2007.05.009

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This review examines the recent literature on the oxidative dehydrogenation (ODH) of ethane and propane, which aims for the synthesis of the corresponding alkenes. The following aspects are discussed: (a) the main features affecting the catalytic properties of systems based on supported vanadium oxide and molybdenum oxide; (b) the characteristics of catalysts producing outstanding olefin yields; (c) advantages in selectivity gained by means of either special reactor configurations or non-conventional conduction of the reaction; (d) the contribution of homogeneous reactions to the formation of olefins during the oxidation of alkanes. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：113 / 131

页数：19

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