Composition, stability, and reactivity of cerium(IV) hydroxotartrato complexes in sulfate solutions

被引：0

作者：

Voskresenskaya, OO ^{[1
]}

Skorik, NA

机构：

[1] Joint Inst Nucl Res, Dubna 141980, Moscow Oblast, Russia

[2] Tomsk State Univ, Tomsk 634050, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2000年 / 45卷 / 12期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The formation and redox decomposition of cerium hydroxotartrato complexes in the Ce4+-SO42--H(4)Tart system was investigated spectrophotometrically, potentiometrically, and kinetically at an ionic strength I = 2 and pH 0.62-3.18 at 22-28 degreesC. Two types of complexes were identified: [CeOHTart](1-) and [(CeOH)(2)Tart](2+) The stability constants and the rate constants of intracomplex redox decomposition were determined for these complexes on the sulfate background. Evidence is shown that the redox process in the systems occurs by the intermediate mechanism through the formation of the aforementioned 1 : 1 and 2 : 1 complexes, which have identical reactivity.

引用

页码：1936 / 1944

页数：9

共 50 条

[31] DETERMINATION OF COMPOSITION AND STABILITY OF TITANIUM(IV) GLUCONATE COMPLEXES
GNATYSHIN, OM
UKRAINSKII KHIMICHESKII ZHURNAL, 1976, 42 (05): : 460 - 463
[32] COMPOSITION AND STABILITY OF OSMIUM(IV)-AMINO ACIDS COMPLEXES
FAROOQ, O
AHMAD, N
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1974, 53 (03): : 461 - 464
[33] Synthesis, Electrochemistry, and Reactivity of Cerium(III/IV) Methylene-Bis-Phenolate Complexes
Mahoney, Brian D.
Piro, Nicholas A.
Carroll, Patrick J.
Schelter, Eric J.
INORGANIC CHEMISTRY, 2013, 52 (10) : 5970 - 5977
[34] CERIUM(IV) HYDROLYSIS IN A SULFATE-SOLUTION
TRUBACHEVA, LV
PECHUROVA, NI
ZHURNAL NEORGANICHESKOI KHIMII, 1981, 26 (12): : 3254 - 3258
[35] NAPHTHIDINES AS INDICATORS IN TITRATIONS WITH CERIUM (IV) SULFATE
SANKEGOWDA, H
SHAKUNTHALA, R
ANALYTICA CHIMICA ACTA, 1977, 91 (02) : 399 - 402
[36] PHOTOMETRIC DETERMINATION OF DIPHENYLAMINE WITH CERIUM(IV) SULFATE
GANDIKOTA, M
RAO, GG
ANALYTICA CHIMICA ACTA, 1973, 67 (02) : 469 - 472
[37] Stoichiometries and stability constants for the cerium(IV) carbonate complexes in dilute aqueous solution
Joao, A
Burrows, H
Ramos, L
Teixeira, H
JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (05) : 531 - 536
[38] Synthesis and reactivity of cerium(IV) silylamido compounds
Williams, Ursula J.
Carroll, Patrick J.
Eric, Schelter J.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
[39] SYNTHESIS, STRUCTURE, AND REACTIVITY OF HOMOLEPTIC CERIUM(IV) AND CERIUM(III) ALKOXIDES
SEN, A
STECHER, HA
RHEINGOLD, AL
INORGANIC CHEMISTRY, 1992, 31 (03) : 473 - 479
[40] Redox and Photochemical Reactivity of Cerium(IV) Carbonate and Carboxylate Complexes Supported by a Tripodal Oxygen Ligand
Pham, Hoang-Long
Jiang, Xinxin
Yan, Qiaolin
So, Yat-Ming
Chan, Wan
Sung, Herman H. Y.
Williams, Ian D.
Leung, Wa-Hung
INORGANIC CHEMISTRY, 2025, 64 (03) : 1433 - 1442

← 1 2 3 4 5 →