Syntheses and properties of thiophene-inserted [3]dendralenes with redox-active 1,3-dithiol-2-ylidene units

被引：11
|
作者：
Hasegawa, Masashi [1 ]
Fujioka, Atsushi [1 ]
Kubo, Takashi [1 ]
Honda, Tomohito [1 ]
Miyamoto, Hisakazu [1 ,2 ]
Misaki, Yohji [1 ,2 ]
机构：
[1] Ehime Univ, Dept Appl Chem, Grad Sch Engn, Matsuyama, Ehime 7908577, Japan
[2] JST, CREST, Matsuyama, Ehime 7908577, Japan
来源：
CHEMISTRY LETTERS | 2008年 / 37卷 / 04期
关键词：
D O I：
10.1246/cl.2008.474
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel dendralene type cross-conjugate molecules based on 1,3-dithiol-2-ylidene units with thiophene have been prepared. The conjugation in the oxidized stage is mainly through the thiophene core, while the cross-conjugated nature is observed in the neutral state. The CT complex of 2a with TCNQF(4) shows moderated electrical conductivity of 10(-4) S cm(-1).
引用
收藏
页码：474 / 475
页数：2
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