Novel synthesis of N-methyl spiropyrrolidines by 1,3-dipolar cycloaddition reaction of azomethine ylides

被引：5
|
作者：
Subramaniyan, G [1 ]
Jayashankaran, J [1 ]
Raghunathan, R [1 ]
机构：
[1] Univ Madras, Dept Organ Chem, Madras 600025, Tamil Nadu, India
来源：
SYNTHETIC COMMUNICATIONS | 2005年 / 35卷 / 16期
关键词：
1,3-dipole; azomethine; ylide; spiropyrrolidines;
D O I：
10.1080/00397910500182572
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of novel N-methyl spiropyrrolidines have been synthesized in good yield by the cycloaddition reaction of azomethine ylides generated by a decarboxylative route from sarcosine and paraformaldehyde with conformationally locked s-trans enone functionality present in the (E)-3-arylidene-4-chromanone as dipolarophiles. The structure of the title compound was established by spectroscopic techniques.
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页码：2189 / 2193
页数：5
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