High-spin carbonyl complexes of iron(i) and cobalt(i)

被引：6
|
作者：
Schneider, Christian [1 ]
Guggotz, Lukas [1 ]
Werncke, C. Gunnar [1 ]
机构：
[1] Philipps Univ Marburg, Chem Dept, Hans Meerwein Str 4, D-35032 Marburg, Germany
来源：
DALTON TRANSACTIONS | 2021年 / 51卷 / 01期
关键词：
AUXILIARY BASIS-SETS; ENERGY; BOND; APPROXIMATION; MONOXIDE; BINDING; CO;
D O I：
10.1039/d1dt03924e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Metal carbonyl complexes are almost exclusively found in a low-spin state due to the strong-field nature of the CO ligand. Here the characterisation of highly labile three-coordinate metal(i) monocarbonyl complexes of iron and cobalt is presented. Experimental and quantum chemical examinations reveal their high-spin configuration.
引用
收藏
页码：179 / 184
页数：6
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