Functionalized β-cyclodextrin as supramolecular ligand and their Pd(OAc)2 complex: highly efficient and reusable catalyst for Mizoroki-Heck cross-coupling reactions in aqueous medium

被引：30
|
作者：
Dindulkar, Someshwar D. [1 ,2 ]
Jeong, Daham [3 ]
Kim, Hwanhee [3 ]
Jung, Seunho [1 ,2 ,3 ]
机构：
[1] Konkuk Univ, Inst Ubiquitous Informat Technol & Applicat UBITA, Seoul 143701, South Korea
[2] Konkuk Univ, Ctr Biotechnol Res UBITA, Seoul 143701, South Korea
[3] Konkuk Univ, Dept Biosci & Biotechnol, Microbial Carbohydrate Resource Bank, 120 Neungdong Ro, Seoul 143701, South Korea
来源：
CARBOHYDRATE RESEARCH | 2016年 / 430卷
基金：
新加坡国家研究基金会;
关键词：
beta-cyclodextrin; Supramolecular catalyst; Mizoroki-Fleck coupling; Reusable catalyst; Aqueous medium;
D O I：
10.1016/j.carres.2016.04.024
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A novel class of water soluble palladium complexes with recognition abilities based on functionalized)3 cyclodextrinhas been synthesized. The complex demonstrated high catalytic activity and a supramolecular platform for phosphine-free Mizoroki-Heck cross-coupling reactions in water. The efficient arylation of alkenes was carried out using different iodo- and bromo-arenes with good to excellent yields (up to 96%). The advantages, like recyclability of catalysts, operational simplicity and accessibility in aqueous medium, make this protocol eco-friendly. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：85 / 94
页数：10
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