Ferromagnetic interaction between copper and terbium ions in pentanuclear cluster [Cu3Tb2(ClCH2COO)12(H2O)8] • 2H2O

被引：1
|
作者：
Voronkova, V. K. [1 ]
Galeev, R. T. [1 ]
Mingalieva, L. V. [1 ]
Novitchi, G. [2 ]
机构：
[1] Russian Acad Sci, Kazan PhysTechn Inst, Kazan 420029, Russia
[2] State Univ Moldova, Kishinev, Moldova
来源：
APPLIED MAGNETIC RESONANCE | 2008年 / 33卷 / 1-2期
关键词：
D O I：
10.1007/s00723-008-0062-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
For the first time the exchange interaction between copper and non-Kramers Tb(3+)ions was studied by means of electron paramagnetic resonance (EPR). Features of the manifestation of this interaction in the EPR spectra of dimer fragments Cu-Tb and pentanuclear fragments Cu-Tb-Cu-Tb-Cu are analyzed. The possibility to determine the sign and value of this interaction from EPR spectra for the case when the lowest states of Tb3+ are the states vertical bar 0 > vertical bar +/- 1 > is shown. The exchange interaction between copper and trivalent terbium ions in the studied pentanuclear complex is ferromagnetic.
引用
收藏
页码：73 / 84
页数：12
相关论文
共 50 条
  • [21] CRYSTAL AND MOLECULAR-STRUCTURE STUDIES OF [CO(H2O)6[2+[CO(H2O)HEDTA](2)-.2H2O AND [CO(H2O)HEDTA].2H2O
    LOTT, S
    ZUBKOWSKI, JD
    VALENTE, EJ
    PERRY, DL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 139 - INOR
  • [22] CRYSTAL STRUCTURES OF [AL2 (OH)2 (H2O)8] (SO4)2 . 2H2O AND [AL2(OH)2(H2O)8] (SEO4)2 . 2H2O
    JOHANSSON, G
    ACTA CHEMICA SCANDINAVICA, 1962, 16 (02): : 403 - &
  • [23] SynthesisandCrystalStructureof[{Cd（hmbdc）(H2O)3}·2H2O]_n
    胡月华
    王燕
    王作为
    李一志
    郑和根
    结构化学, 2007, (04) : 423 - 426
  • [24] Ni(C2(COO)2)(H2O)4 • 2H2O and Ni(C2(COO)2)(H2O)2:: Two co-ordination polymers of the acetylenedicarboxylate dianion
    Hohn, F
    Billetter, H
    Pantenburg, I
    Ruschewitz, U
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2002, 57 (12): : 1375 - 1381
  • [25] Copper(II) acetate monohydrate Cu(CH3COO)2•H2O
    Young, JA
    JOURNAL OF CHEMICAL EDUCATION, 2005, 82 (07) : 990 - 990
  • [26] CRYSTAL STRUCTURES OF Ln（o-HOC6H4CO2）3 （H2O）2·2H2O [Ln =Tb,Ho]
    Ma Jian-Fang Jin Zhong-Sheng Ni Jia-Zuan Changchun Institute of Applied Chemistry
    结构化学, 1991, (02) : 125 - 128
  • [27] Synthesis and crystal structure of a macrocycle [Cu(dadm)(mal)(H2O)2•2H2O
    Lin, ZZ
    Jiang, FL
    Chen, L
    Hong, MC
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (09) : 993 - 996
  • [28] HydrothermalSynthesisandCrystalStructureof[Cu（en）2（H2O）]2{PW11.5Cu0.5O40[Cu（en）2]}·2H2O
    李明雪
    王凯华
    牛景扬
    结构化学, 2008, (03) : 340 - 344
  • [29] ON THE THERMAL-DECOMPOSITION OF [FE2NIO(CH3COO)6(H2O)3].2H2O
    LANGBEIN, H
    EICHHORN, P
    JOURNAL OF THERMAL ANALYSIS, 1991, 37 (05): : 993 - 1003
  • [30] Crystal Structure of [Cu(C21H25N2O4) （H2O）2]·NO3·2H2O
    Wu Jie-Ying
    Xie Fu-Xin
    Tian Yu-Peng
    Chen Yao
    Ni Shi-Sheng
    Du Shao-Wu
    Wu Xin-Tao (Department of Chemistry. Fuyang Normal College
    结构化学, 1995, (04) : 250 - 254
12345