6-Amino-1,3-dimethyl-5-[(E)-2-(methylsulfanyl)benzylideneamino]pyrimidine2,4(1H,3H)-dione

被引：7

作者：

Booysen, Irvin ^{[2
]}

Muhammed, Ismail ^{[2
]}

Soares, Anna ^{[2
]}

Gerber, Thomas ^{[1
]}

Hosten, Eric ^{[1
]}

Betz, Richard ^{[1
]}

机构：

[1] Nelson Mandela Metropolitan Univ, Dept Chem, ZA-6031 Port Elizabeth, South Africa

[2] Univ Kwazulu Natal, Sch Chem, ZA-3209 Pietermaritzburg, South Africa

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

GRAPH-SET ANALYSIS; CRYSTALS; PATTERNS;

D O I：

10.1107/S1600536811020903

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C14H16N4O2S, is a Schiff base derivative of 2-(methylsulfanyl)benzaldehyde. The configuration about the C=N double bond is E. The heterocyclic ring is essentially planar (tau = 3.1 degrees) and makes a dihedral angle of 12.24 (7)degrees with the benzene ring. An intramolecular N-H center dot center dot center dot S hydrogen bond is observed. In the crystal, N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds link molecules into layers perpendicular to [101]. The closest distance between the centroids of two heterocyclic rings was found to be 3.5268 (8) degrees.

引用

页码：O1592 / U2043

页数：11

共 50 条

[31] Synthesis and antiviral evaluation of 1,3-dimethyl-6-(1H-1,2,3-triazol-1-YL)pyrimidine-2,4(1H,3H)-dione derivatives
A. Sh. El-Etrawy
A. A.-H. Abdel-Rahman
Chemistry of Heterocyclic Compounds, 2010, 46 : 1105 - 1108
[32] SYNTHESIS AND ANTIVIRAL EVALUATION OF 1,3-DIMETHYL-6-(1H-1,2,3-TRIAZOL-1-YL)PYRIMIDINE-2,4(1H,3H)-DIONE DERIVATIVES
El-Etrawy, A. Sh.
Abdel-Rahman, A. A. -H.
CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2010, 46 (09) : 1105 - 1108
[33] Crystal Structure of 5,5'-(Furan-2-ylmethylene)bis(6-amino-1,3-dimethylpyrimidine-2,4(1H,3H)-dione) (vol 65, pg 875, 2020)
Sharma, Naresh
Brahmachari, Goutam
Gupta, Vivek K.
CRYSTALLOGRAPHY REPORTS, 2021, 66 (01) : 174 - 174
[34] 6-Amino-1,3-dimethyl-5-(4-methylthiazol-2-yldiazenyl)uracil
Seferoglu, Zeynel
Hokelek, Tuncer
Sahin, Ertan
Ertan, Nermin
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O571 - O573
[35] (E)-5,5′-(3-Phenylprop-2-ene-1,1-diyl)bis[6-amino-1,3-dimethylpyrimidine-2,4(1H,3H)-dione] : Synthesis, characterization, crystal structure and antimicrobial activity
Roy, Subhadip
Banik, Rupak
Das, Subrata
Thakur, Ashim Jyoti
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2014, 91 (11) : 2117 - 2125
[36] Pyrrolopyrimidines.: 3.: 5-amino-1,3-dimethylpyrrolo[3,2-d]pyrimidine-2,4(1H,3H)-dione
Tkachenko, YN
Tsupak, EB
Pozharsky, AF
KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1999, (03): : 375 - 380
[37] Quinazoline-2,4(1H,3H)-dione
Liu, Ge
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1677 - U1217
[38] 1-(4-tert-Butylbenzyl) pyrimidine-2,4(1H, 3H)-dione
Wang, Hong-Sheng
Li, Gong-Chun
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1047 - +
[39] PTERIDINE .81. MECHANISM OF THE PHOTOOXIDATION OF 5,6-DIHYDRO-1,3-DIMETHYL-6-THIOXOPTERIDINE-2,4(1H,3H)-DIONE
HECKEL, A
PFLEIDERER, W
HELVETICA CHIMICA ACTA, 1986, 69 (05) : 1088 - 1094
[40] 6-[(dimethylamino)methyleneamino]-1,3-dimethylpyrimidine-2,4(1H,3H)-dione dihydrate
Das, Subrata
Saikia, Binoy K.
Sridhar, B.
Thakur, Ashim J.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1662 - U1097

← 1 2 3 4 5 →